, , A'maxV A'maxp . , , , . . .
:
d In K/dT = Q/RT2. (217)
R,
d lg K/dT = Q /19,147 103 T2.
, , (Q > 0), . . . (. . Q < 0) .
( ) ( ), .
10. ln K = f(T) 'max = φ(T)
, , , ln = f (), . d In K/dT = Q/RT2 Q = const.
ln = Q/RT + ,
. , , Q ( ) , , :
.
R,
(218)
(218) , Q , , 2, K1.
, , . Q Q = f () = f (T)
d ln K/dT = Q/RT2 = (Q0 + αT + βT2 + γT3)/RT2
d ln = Q0 dT/RT2 + αdT/RT + βdT/R + γT dT/R.
,
(219)
.
(219) R ,
. (220)
(219) (220) , Q0 . , , , .
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A'm = φ() (219) (214).
(214) ln , A'max = φ(), . .
(221)
, A'm ΔF0 ΔG0, a Q0 ΔU0 ΔH0,
(222)
. (223)
(221)(223), (219), , ( ). ΔU0 ΔH0 .
18