2
. , . . , .
(n) , lgP0 n (. 9.1).
. 9.1. - -
, , . -
, , :
,
,
,
,
,
.
, . , , , , . , , , .
< pKa - 2 99% (D P0), . > pKa + 2 99% . .
> pKBH+ + 2, < pKBH+ - 2 .
.
, . 9.2.
. 9.2 (1), (2) (3)
Po( ) =100, Po( ) 0;
pKa =7, pKBH+ = 7; (pKa =5, pKBH+ = 9).
V/Vo . , 99% , D = 5, 20 . , R 83%.
|
|
, . . .
= =
(1-R) y, .. y2. n- yn.
= Rn = 1 -
99% , D = 5, 10 , 3 10 (.. 30 , 6 , ).
( ) . , , ( ), .
(), (). , - .