, (NH3), .
:
: 3NH2 ( ), (3)2NH ( ), (3)3N ( ) ..
: 1) ; 2) (NH2); 3) .
. , , . . , , .
.
.
1. :
, . , .
2.
CH3NH2 + 1 = [CH3NH3]C1 [CH3NH3]+ + l-
, , :
[CH3NH3]C1 + NaOH = CH3NH2↑ + NaCl + H2O
3. .
4. ( , N-):
RNH2 + HNO2 → ROH + N2↑ + H2O,
R2NH + HNO2 → R2NNO + H2O.
.
1. 12O3 :
ROH + NH3 → R NH2 + H2O.
2. () , :
CH3Br + 2NH3 → CH3NH2 + NH4Br
:
CH3NH2 + 3r + NH3 → (CH3)2NH + NH4Br
:
65NH2
( ), ( )
. , , .
. , .
π- ( ), .
, .
I. :
II. . I (-, - ):
2,4,6-
|
|
. :
렠
, . .
, ( ).