, , , .
( ):
[(C4H9)N4]2 [Co(SCN)4]; [Ba(OH2)6]× RSO3;
[d(phen)2] (RCOO)2, (phen );
, . ( ) , , , , -, .
( ), , .
, - , , . , .
, , , . :
[Ag(NH3)2]NO3 [Ag(NH3)2]+ + NO3-
- . .
, . , , (K). (bn, n ), (. 5.1).
. 5.1
[Ag(NH3)]+ | lgK1 = 3,32 | |
[Ag(NH3)2]+ | lgK2 = 3,91 | = =1,7×107 lgb2 = lg K1 + lgK2 = 7,23 |
( !), .
,
, , , ( ). , MLn
- . , () .
|
|
5.4.
, , , , , ( , .)