547: 664.951(076)
.., ...,
.., ...,
260800.62 __________________ 2013, .
-
260800.62 .
- , , , , .
, , .
2- , 6 3 .
1.
1.1.
:
- , , , , ;
- ;
- ; ;
- ;
- .
, , .
|
|
|
, , .
.
. , 2865, 6 ( ) 5 ( ) : 5, 19, 24, 37, 50, 53, 66, 79, 82 95.
, .. ( 110, 1120, 2130 . .) , . , 2865, 21-30 24.
| 10,17,21,38 42,59,65,73,84,96 | 1,11,24,31 44,51,61,7181,91 | 2,12.21,32 42,52,62,72,82,92 | 3,13,23,33 43,53,63, 73,83,93 | 4,14,24,34 41,54,64, 74,84,94 | 5,15,25,35 45,55,65, 75,85,95 | |
| 10,20,30,40 50,60,70, 75,88,100 | 1,12,23,34 45,56,67, 78,89,100 | 2,13,24,35 46,57,68, 79,90,91 | 3,14,25,36 47,58,69, 80,81,92 | 4,15,26,37 48,59,70, 71,82,93 | 5,16,27,38 49,60,61, 72,83,94 | |
| 10,11,22,33 44,55,66, 77,88,99 | 1,20,29,38 47,56,65, 74,83,92 | 2,11,30,39 48,57,66, 75,84,.93 | 3,12,21,40 49,58,67, 76,85,94 | 4,13,22,31, 50,59,68 77,86,95 | 5,14,23,32 41,60,69, 78,87,96 | |
| 10,19,28,37 46,55,64, 73,82,91 | 1,13,25,37 49,51,63, 75,87,99 | 2,14,26,38 50,52,64, 76, 88,100 | 3,15,27,39 42,54,66, 78,90,92 | 4,16,28,40 41,53,65, 77,89,91 | 5,17,29,31 43,55,67 77,89.91 | |
| 10,11,23,35 47,58,70, 79,87,95 | 1,11,23,35 47,58,70, 79,87,95 | 2,12,24,36 48,60,70, 78,86,94 | 3,13,25,38 49,59,68, 77,85,93 | 4,14,27,40 50,59,67, 74,81,91 | 5,15,28,39 46,53,61, 72,82,96 | |
| 10,20,22,37,43,51,64,75,90,100 | 1,14,27,40 47,52,63, 76,83,91 | 2,15,28,39 46,51,64, 77,81,94 | 3,16,29,32 50,52,66, 79,86,92 | 4,17,30,31 45,58,70 73,82,98 | 5,16,21,36 49,53.61, 74,90,100 | |
| 10,13,26,38 44,60,65, 78,87,100 | 1,15,29,33 46,59,62, 75,88,91 | 2,16,30,34 47,60,63, 76,89,92 | 3,17,21,35 48,51,64, 77,90,93 | 4,18,22,36 44,52,65, 78,81,94 | 5,19,24,37 50,53,67, 79,82,95 | |
| 10,14,23,31 42,58,70, 74,87,100 | 1,16,30,34 48,56,69,74,83,94 | 2,18,21,31 44,50,64, 71,84,91 | 3,19,22,35 47,59,62, 77,82,92 | 4,11,24,38 42,57,63, 72,88,93 | 5,20,23, 37,41,54, 6378,81,99 | |
| 10,17,26,39, 43,55,67,76, 90,97 | 1,17,21,36, 42,54,67, 73,86,91 | 2,19,22,33, 49,51,64, 80,85,93 | 3,20,27,34, 50,56,62, 78,83,96 | 4,11,25,40, 44,55,68, 74,87,92 | 5,12,26,31, 47,59,63, 77, 90,95 | |
| 10,18,30,39, 46,58,69,76, 84,98 | 1,18,22,39, 43,60,66, 74,85,97 | 2,19,23,40, 44,51,67, 75,86,98 | 3,20,24,31, 45,52,68, 76,87,99 | 4,11,25,32, 46.53,69, 77,88,100 | 5,12,26,33, 47,54,70, 78,89,91 |
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| 6,15,26,36, 46,56,66,76, 86,96 | 7,16,27,37, 47,57,67,77, 87,97 | 8,18,28,38, 48,58,68,78, 88,98 | 9,19,29,39, 49.59,69,79, 89,99 | |
| 6,17,28,39, 50.51,62,73, 84,95 | 7,18,29,40, 41,52,63,74, 85,96 | 8,19,30,31, 42,53,64,75, 86.97 | 9,20,26,32, 43,54,65,76, 87,98 | |
| 6,15,24,33, 42,51,70,79, 88,97 | 7,16,25,.34, 43,52,63,80, 89,98 | 8,17,26,35, 44,53,62,71, 90,99 | 9,18,27,.36, 45,54,63,72, 91,100 | |
| 6,18,30,32, 44,56,68,80, 82,94 | 7,19,21,33, 45,57,69,71, 83,95 | 8,20,22,34, 46,58,70,72, 84,96 | 9,12,23,36, 48,60,62,74, 86,98 | |
| 6,16,29,31, 44,57,69,80, 88,92 | 7,17,30,32, 45,60,62,73, 80,97 | 8,18,26,34, 41,54,64,71, 84,98 | 9,19,24,33, 42,55,65,80, 83.99 | |
| 6,19,24,.37, 41,56,69,80, 84,95 | 7,20,22,33, 42,56,62,71, 85,96 | 8,11,23,34, 48,54,68,75, 89,97 | 9,12,23,35, 43,57,63,76, 88,99 | |
| 6,20,25,38, 41,54,67,71, 83,96 | 7,11,26,39, 43,56,69,71, 84,97 | 8,12,27,40, 47,53,67,72, 85,98 | 9,13,28,39, 48,54,65,73, 86,99 | |
| 6,12,29,33, 48,52,68,73, 89,95 | 7,13,28,32, 49,53,61,75, 85,96 | 8,14,27,36, 44,58,65,80, 86,100 | 9,15,23,40, 43,54,66,79, 83,98 | |
| 6,13,28,32, 48,60,61,75, 88,99 | 7,14,29,35, 43,52,65,79, 81,94 | 8,15,24,37, 41,53,70,72, 89,97 | 9,16,25,38, 45,55,66,71, 81,98 | |
| 6,13,27,34, 48,55,61,79, 90,92 | 7,14,28,35, 49,56,62,80, 81,93 | 8,15,29,36, 50,57,63,71, 82,94 | 9,16,30,37, 41,53,64,72, 83,96 |
1.2
. (1-10) , [1-6].
.
[1-7].
(11-20) , , (, , , , , , , -) . . , , a b- , , , , . . , , , - . , (, . .), . , [1,3-7].
. , , . , ( ). , [1,3-7].
, , , , , . , , [1-6].
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(31-40) (, ) , . , (, ) () [4,5].
(41-50) ( ) . [1,4].
(71-80) , , , [1,2, 4,10, 11,14].
(61-70; 81-90; 91-100) , , [1, 3, 4]., [12, 13].
2.
1-10.
) . , .
) .
) .
) ( ), .
) .
) , .
11-20. . , :
11. ) -1 +
[O]
) ¾
t
) α- ¾
12. ) -1 + NN2
) + N
t
) a- ¾
13. ) + Br2
) + (3)2
t
) ¾
14. ) -2 +
) + N
t
) ¾
15. ) + O
) - + FeCl3
[O]
) ¾
16. ) + Br2
) + ()2
t
) γ- ¾
17. ) + SOCl2
t
) ¾
[O]
) ¾
18. ) + H2N-NH-65
t
) ¾
[O]
) ¾
19. ) + NaHSO3
) + HNO2
t
) a- ¾
20. ) + NH3
[]
) -2 ¾
t
) α- ¾
21-30. , , , . . .
21. ) --2-2-;
) 3-=N-3.
22. ) -2-2---511;
|
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) (3)2=N-N- 65
23. ) 3-S3;
) (3)2=N-N2.
24. ) (3)2-2;
) 3-=N-N- 65.
25. ) 3----2- 3;
) 3-=N-.
26. ) 3-2--N-3;
) (3)2=N-N=(3)2.
27. ) NaO-2-CH2 Na;
) 65-2---65
28. ) Cl-CO-2-;
) 25--N=.
29. ) N-2-2-2-N;
) HO-2-CH-2--3.
30. ) (3)2H-l
) -Na-O-C6H4-O-Na
31-40. . , (), Na, ()2, FeCl3, .
41-50. . .
41. ; .
42. 2- ; -2.
43. ; 1,3-.
44. a- ; -2.
45. 1,2-, -2.
46. -1,2- ; 2,3-.
47. ; 1,2-.
48. a- ; -1,3.
49. 2,3--1,3; 1,3-.
50. ; 1,3-.
71-80. , . . , , ; .
; (-H2-CH=CH-CH2-)n
61-70. ( ). ? - (, , , ).
61. ) D-; ) ; ) .
62. ) D-; ) ; ) .
63. ) D-; ) ; ) .
64. ) D-; ) ; ) .
65. ) D-; ) ) .
66. ) D-; ) ; ) .
67. ) D-; ) ; ) .
68. ) D-; ) ; ) .
69. ) D-; ) ; ) .
70. ) D-; ) ; ) .
81-90. . , , . .
81. ) ; ) .
82. ) ; ) .
83. ) ) α-.
84. ) ; ) .
85. ) ; ) .
86. ) ; ) .
87. ) ; ) .
88. ) ; ) .
89. ) ; ) .
90. ) ; ) .
91-100. , . ? ? ?
91. ---.
92. ---
93. ---.
94. ---.
95. ---.
96. ---.
97. ---.
98. ---.
99. ---.
100. ---.
1. .., .. . .: . .,1985. 510.
2. .. . : . ., 2003. 605.
3. .., .., .. . .: . .,2002. 623.
4. .. . : . ., 2001. 672.
5. ., . . .:,1974. 1132.
6. .. . .:. .,1976. - .2. 281.
7. .., .. . - ., 1994. 432 .
8. .. . .: , 1990. 272 .
9. . ., 1, 1998; - 623; 2, 1998, 1134; 3, 1992, 639.; 4,1995, 639.; 5, 1999, 783.
10. . ., 1983. 931.
11. . - .1-3. : , 1976. 592.
12. .. . - .: , 1999. - 507.
13. . . .: ,1974. 957.
14. . . .:, 1997. 396.
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...................................................................................................
1.
.......................................................................................3
1.1. ..3
1.2. ............7
2. 酅............9
3. ..............20
..
..
2.
