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ω , % ( )
B 5*103 Na2B4O7 10 H2O (); Na2B4O7 10 H2O (); H3BO3 ()
Al 8,8 : KAlSi3O8 (); KH2Al3Si3O12 (); NaAlSiO4 (); H4Al2Si2O9 (); Al2O3 nH2O (); Na3[AlF6] (); Al2O3 ( ( r), ( Ti Fe))
Ga 1,5*103 CuGaS2 (); Al, Zn, Fe
In 1,4*105 FeIn2S4 (); CuInS2 (); Zn
Tl 3*104 TlAsS2 (); (Tl,Cu,Ag)2S (); Zn, Fe, Pb

53

Ͳ Ҳ

 

B Al Ga In Tl
         
(% ) 10(19) 11(81) 27(100) 69(61,2) 71(38,8) 113(4,33) 115*(95,67) 203(29,5) 205(70,5)
, 8,2981 5,9858 5,998 5,7864 6,1080
, 0,30 0,2 0,39 0,2 0,32
2,01 1,47 1,82 1,49 1,44
3; +3 +3 +1; +2; +3 +1; +2; +3 +1; +3

 

54

 

Ͳ Բ-ղ̲Ͳ Ҳ

B Al Ga In Tl
( ) , () ( -) () (-) (-)
-
, ρ, /3 (293 ) 2,34 2,70 5,90 7,31 11,85
, 0     29,78 156,17 303,5
, 0          
               

 


ղ̲Ͳ Ҳ ҲI-

55

ֲ

 

  ,
  , t → ; Al, Ga, In, Tl →
H2
Hal B, Al → EHal3; Ga, In, Tl → EHal, EHal3
O2, t B, Al, Ga, In → E2O3; Tl → Tl2O, Tl2O3
S, t B, Al, Ga, In → E2S3; Tl → Tl2S, Tl2S3
N2, t B, Al → EN
P, t = 500 10000 B, Al, Ga, In → EP Tl → Tl3P, TlP3; TlP5
C, t ≥10000C B → B4C3; Al → Al4C3

56

 

ֲ ²

 

  ,
  H2O, t ≤1000C
HCl B → ; Al, Ga, In → ECl3; Tl → TlCl
H2SO4 () B → ; Al → ; Ga, In → E2(SO4)3; Tl → Tl2SO4
H2SO4 () B → ; Al, Ga, In → E2(SO4)3; Tl → Tl2SO4
HNO3 () B → H3BO3; Al → ; Ga, In → E(NO3)3; Tl → TlNO3
HNO3 () B → ; Al, Ga, In → E(NO3)3; Tl → TlNO3
NaOH () → NaBO2; Al, Ga, In → Na[E(OH)4]; Tl →

 

57

 

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Ҳ -

B 1) . 2) . 3) , .
Al 1) . 2) .
Ga , , , .
In
Tl

 

 

V-

 

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