1. F2() + 2ClO2() = 2ClO2F() .
(1 , 2 ) | |
3 |
2. 2NO() + Cl2() = 2NCl()
(1. v = k∙NO∙Cl2, 2. v = k∙NO2∙Cl2, 3. v = k∙2NO∙Cl2, 4. v = k∙NOCl2) | |
2 |
3. A + B = :
, / | ||||
, / | ||||
v, /(∙) | ? |
, |
4. 2 + = 2D :
, / | |||
, / | |||
v, /(∙) |
(1. v = k∙∙; 2. v = k∙∙2; 3. v = k∙2∙; 4. v = k∙2) | |
5. 222() = 2H2O() + O2() 500 :
2O2, / 0,2 0,4 0,2
v, /(∙) 0,1 0,2 0,1
(1. v = k∙220; 2. v = k∙22; 3. v = k∙222; 4. v = k∙22∙2) | |
0,5 |
6. 2N2O() = 2N2() + O2() 665 N2O :
N2O, / 0,2 0,4
v, /(∙) 9∙105 1,8∙104
4,5∙104 |
7. 2N2O5() = 4N2() + O2() 45 N2O5 :
N2O5, / 0,2 0,4
v, /(∙) 1∙104 2∙104
(1. v = k∙N2O50; 2. v = k∙N2O5; 3. v = k∙N2O52) | |
5∙104 |
8. 24Cl2() = C24() + Cl2() 360
24Cl2 :
24Cl2, / 0,2 0,4
v, /(∙) 3,34∙105 6,68∙105
(1. v = k∙24Cl20; 2. v = k∙24Cl2; 3. v = k∙24Cl2; 4. v = k∙24Cl22) | |
16,7∙105 |
9. 2NO() + O2() = 2NO2() 660 :
NO, / 0,01 0,01 0,03
|
|
O2, / 0,01 0,02 0,02
v, /(∙) 2,5∙103 5,0∙103 4,5∙102
2,5∙103 |
10. 2NO() + 22() = N2() + 22() 1000 :
NO, / 0,12 0,12 0,02 0,04
2, / 0,02 0,04 0,12 0,12
v, /(∙) 0,2 0,4 0,3 1,2
11. 24Br2 + 3KI = C2H4 + 2KBr + KI3 60 C :
C(24Br2), / 0,5 0,5 1,5
C (KI), / 1,8 7,2 1,8
v, /(∙) 0,269 1,08 0,807
0,3 |
12. 2Co3+ + Tl+ = 2Co2+ + Tl3+ 20 ºC :
Co3+(/): | 0,1 | 0,3 | 0,4 | 0,3 | 0,3 |
Tl+(/): | 0,1 | 0,1 | 0,1 | 0,2 | 0,3 |
(. .): |
13.
3() = 4() + O()
800 :
3, / 0,2 0,4
v, /(∙) 1,8∙106 7,2∙106
4,5∙105 |
14. C2H4() + Br2() = C2H4Br2()
2. 25 1,7∙104 /(∙).
(1. v = k∙24∙Br2; 2. v = k∙C2H4∙Br22; 3. v = k∙C2H42∙Br2; 4. v = k∙C2H4) | |
50 | 9,6∙104 |
15. 23() = 32() 0 1,41∙102 1
1,38∙103 1 27 .
0 0,1 / | 14,1 |
2,33 |
16. 2N2O5() = 2N24() + O2() 0 7,9∙107 1 4,9∙103 1 65 .
65 N2O5 0,5 / | 2,45∙103 |
2,69 |
17. 3, 4. ,
10 (T = const) | |
30 (P = const) |
18. 2, 3. ,
6 (T = const) | |
40 (P = const) |
|
|
19. 2, 4. ,
10 (T = const) | |
20 (P = const) |
20. 3, 2,5. ,
6 (T = const) | |
60 (P = const) |
21. 2, 3. ,
5 (T = const) | |
50 (P = const) |
22. N2O4() = 2NO2() 7∙103 1 1 4,8∙104 1 25 .
(1. v = k∙N24; 2. v = k∙N22; 3. v = k∙N2O42) | |
2,2 |
23.
2NO2() = 2NO() + O2()
50 5,3 .
1,4 |
24.
() = 2() + ()
3,8∙104 1 15 , 82,5 /.
(1. v = k∙O; 2. v = k∙O∙2; 3. v = k∙2) | |
25 | 1,2∙103 |
25.
2NO() + Cl2() = 2NOCl()
5,4 2/(2∙) 0 , 1,05∙102 2/(2∙) 150 .
3 (T = const) | |
(/) |
26.
C2H2() + 2() = C2H4()
1,14×102 /(×) 500 , 80 /.
(1. v = k∙22∙2; 2. v = k∙C2H2∙22; 3. v = k∙C2H22∙2; 4. v = k∙C2H2) | |
550 | 6,2∙102 |
27. : CH3NH2 = HCN + 2H2, : v = k∙CH3NH2.
593 1,0∙103 1, 1,5∙102 1 667 .
593 3NH2 0,1 / | 104 |
(/) | 247,5 |
28. C2H5Br() = C2H4() + HBr() 218 /. ,
300 350 |
29. C2H5Cl() = C2H4() + HCl() 247,5 /. ,
350 400 |
30. 2N2O5() = 2N2O4() + O2() 103,5 /. ,
(V) | |
298 318 | 13,85 |
31. N2O4() = 2NO2() 54,4 /. ,
0 15 | 3,5 |
|
|
32. C2H4() + 2() = C2H6() 180,5 /. ,
350 400 |
33. ,
325 + = 3 + 25,
. 47 /. ,
20 40 | 3,4 |
34. 3Br + I = 3I + Br 76,6 /. , :
- | |
20 35 | 4,6 |
35. 24() = 22() + 32() v = k∙[4]. 800 6∙107 1, 330 /.
4 | |
1000 | 2∙104 |
36. () = 2() + () ( = const). 510 607 3,6∙106 9,0∙105 /(∙), .
(/) |
37. CO() + Cl2() = COCl2()
v = k∙[CO]∙[Cl2]3/2. 350 3,81; 48 /.
4 | |
400 | 7,6 |
38. 2NO2() = 2NO() + O2() 1,5 /(∙) 330 8,0 /(×) 380 .
(/) | 109,5 |
39. 25Br() = C2H4() + HBr() 5,9∙104 1 395 2,5∙103 1 420 .
420 25Br 0,2 / | 5∙104 |
(/) | 222,2 |
40. 2OF2() = 2F2() + O2() 1,4∙102 /(∙) 250 5,7∙102 /(∙) 270 .
250 OF2 0,2 / | 5,6∙104 |
(/) | 165,7 |
41. 2NO2() = 2NO() + O2() 84 ∙1∙1 600 336 ∙1∙1 620 .
(/) | 214,3 |
42. 285 3 , 305 - 45 .
(/) |
43. 2N2O5 = 2N24 + O2 7,8∙107 273 1,7∙105
293 .
4,67 | |
(/) | 102,4 |
44. 2HI() = H2 + I2 1,2∙106 /(∙) 575 8,6∙105 /(∙) 647 .
|
|
1,81 | |
(/) |
45. 3() = 4() + O() 647 23,0 /(∙), 44,8 /(∙) 663 .
1,52 | |
(/) |
46. 2NO() + Br2() = 2NOBr() 2,1∙103 2/(2∙) 265 2,7∙103 2/(2∙) 288 .
1,1 | |
(/) | 6,93 |
47. ( ) 20 4,4∙106, 50 2,3∙104.
3,74 | |
(/) | 103,7 |
48.
325 + = 3 + 25
0 0,0195, 25 0,1093.
(/) | 46,6 |
49.
222() = 2H2O() + O2
v = k∙[H2O2]. 75,4 /, ( ) 49 /. ,
22 | |
50. 2HI() = H2() + I2() v = k∙[I]2.
184 /, () 107 /. ,
8,64∙1013 |