1) ; 2) .
1 : . :
2() + () = 2 + 2 .
J = -d./dt = k[2][]
, .
[2]=[ ]= 1 /, J = k.
1. , . , .
.. . [ J ] = [/(×)]. [/].
2 + = 2 + 2
J = k × [2] × []
[/(×)] = [ k ] [/] [/]
: [ k ] = /× = ×-1×-1.
+ bB
J = k ××Bb (1)
[/(×)] = [ k ] [/] [b/b]
[1/] = [ k ] [a-1/a-1] [b/b]
[ k ] = [+b-1/-1b]
[ k ] = [+b-1 (+b-1) -1]
- 1: ,
b B,
, . 0 :
1) ; 2) 2 - , , . , .
( ) , , , .
, . 1:
n = + b.
+ b = 1 1- , 2 , 3 . 4- , , .. 4- .
. .
k = z exp(-E/RT)
R = 8,31, = 2,72
(), Z , , .
, .. , ( ) . , .
|
|
|
- , ( ) , .
2 - .
:
k1
+ bB cC + dD
k-1
J = k1 ××Bb
J = k-1 ××Dd
k-1 , , .
J = J .
-.
, , , .
.. J = J,
k1 ××Bb = k-1 ××Dd
k1/k-1 = ×Dd/×Bb = . ( ).
+ bB cC + dD
k-1
