, ,
:
t 0
(CH 2)6 N 4 + 2 H 2 SO 4 + 6 H 2 O → 6 HCOH ↑ + 2 (NH 4)2 SO 4
= .
H2SO4 + 2 NaOH → 2 H2O + Na2SO4
f . = M 1/ z =
-
,
:
(CH2)6N4 + HCl → (CH2)6N4HCl
.
f. = M1/z =
,
Glucosum
Glucosum anhydricum
C 6 H 12 O 6
CH 2 OH 
O H
O \\ /
H C
H H |
H C OH
HO OH H OH |
HO C H
|
H OH H C OH
|
H C OH
|
CH 2 OH
)
Π ʠ
Ѡ t0
()4 +2 u + Na͠ Cu2 +
2͠
Na
Π ʠ
Ѡ
Na ͠
+ ()4 + 2
2
Na
)
)
Π t0
R - C + 2[ Ag (NH 3)2] OH RCOONH 4 + 2 Ag ↓ + H 2 O + 3 NH 3 ↑
) ( (II) ) - .
Π
R + 2[ HgI 4 ] + 3 R + Hg ↓ 4 I + 22
͠
) -
1.
2. - :
) 5%
|
|
|
,
:
.
Π
R - Ѡ + I 2 + 3 Na → R - Ѡ + 2 NaI + 22
. Na
I2 + 2 N2S23 = 2 NI + N2S46
I2 + 2 → 2 I-
2 S23 2- - 2 → 2 S462-
f .= M 1/ z =
) 5% -
N. B.! , !!!
, 5% , .
:
- 5,2
- 8,3% - 4,4
- 1000
1 1 : 0,26; 0,1 5
, .
↓ ↓
蠠
- -
- -
() ()
-
(
)
,
*
Diphenhydramine Hydrochloride *
Dimedrolum
C6H5 CH3
\ /
CH O CH2 CH2 N HCl
/ \
C 6 H 5 CH 3
ß
1.
2.
3.
4.
C6H5 CH3 C6H5 CH3
\ / \ + /
CH O CH2 CH2 N + H2SO4 → CH O CH2 CH2 N HSO4-
/ \ / | \
C6 H5 CH3 C6 H5 H CH3
C6H5 CH3
\ + + /
→ CH O CH2 CH2 N SO42-
/ | / \
C6 H5 H H CH3
-
5. -
R3 N HCl + AgNO3 → AgCl↓ + R3 N HNO3
|
|
|
6. :
-
-
-
:
O
//
C6H5 CH3 CH3 C C6H5 CH3 O O
\ / \ \ +/ // //
CH O CH2 CH2 N HCl + HClO4 + O → CH O CH2 CH2 N ClO4 + CH3 C +CH3 C
/ \ / / / \ \ \
C6H5 CH3 CH3 C C6H5 H CH3 Cl
. \\
O
f . = M 1/ z =
-
) ,
:
R3N HCl + NaOH → NaCl + R3N + H2O
.
f . = M 1/ z =
)
:
R3 N HCl + AgNO3 → AgCl↓ + R3 N HNO3
.
f . = M 1/ z =
