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2. " " 7353 18.11.2005. http://gska2.rada/gov.ua/pls/zwsb_ii/webproc4_l?id=&pf3511=24299.
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11.08.2008.http://www.mdoffice.com.ua/pls/MDOffice/all_news.printnews?dat=11082008&num=67812.
4. " (, ) " 4145 03.03.2009. http://gska2.rada/gov.ua/pls/zwsb_n/ webproc4_1?id=&pf3511=34627.
5. " (, ) " 4145 03.03.2009. http://gska2.rada/gov.ua/pls/zwsb_n/webproc4_1?id=&pf3511=34627.
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7. . . / . . . - 5, 2000, . 100-101.
8. .. : / .. . "³" 547. - , 2005, C. 161-162.
9. .. / .. . " " 1, 2002, C. 52-61.
10. .. Գ- / .. . " ". . 9, . 2. , 2007, C. 514-523.
11. .. / .. . " " 2 (), 2001, C. 4753.
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| 546.214:66.094.3+544.47:546.3 .., .., .. CrIII . CrIII CrVI . . | |||||
| 546.214:66.094.3+544.47:546.3 .., .., .. CrIII . CrIII CrVI . . | |||||
| UDK 546.214:66.094.3+544.47:546.3 Tyupalo N.F., Bondar V.V., Shapovalova I.N. About the mechanism of CrIII catalityc oxidation by ozone in sulfuric acid solution. The analysis of the mechanism of CrIII in CrVI oxidation reaction by ozone in presence of the transition metals has been carried out. The possibility of mechanism realization in one three-electronic stage has been shown at first. | |||||
| 542.943.7:541.124-145.15:547.536.214 .. 3,4- . 3,4- (II) . . - . . 2, . 2, . 4. | |||||
| 542.943.7:541.124-145.15:547.536.214 .. 3,4- . 3,4- (II) . . - . . 2, . 2, . 4. | |||||
| UDK 542.943.7:541.124-145.15:547.536.214 Potapenko E.V. Catalytic oxidation of 3,4-dynitrotoluene of ozone in the liquid phase. The reaction of ozonation of 3,4-dinitrotoluene in acetic acid in the presence of manganese acetate (II) and sulfuric acid. The kinetic parameters of the main stages of the catalytic cycle. Proposed a mechanism for redox catalysis. Fig 2, Tab. 2 Sour. 4. | |||||
| 541.127: 542.943 .., .. 4- . 4- . , 4-. (71%), 4- 4-, 26%. .4, . 5, . 3. | |||||
| 541.127: 542.943 .., .. 4- . 4- . , 䳺 4-. (71%), - 4- 4-, 26%. .4, .5, . 8. | |||||
| UDK 541.127: 542.943 Galstyan A.G., Zioma I.A. Investigation of the ozonolysis 4-aminotoluene in acetic anhydride. The reaction of ozone with 4-aminotoluene in acetic anhydride. It is shown that in acetic anhydride substrate rapidly acylated in the preparation of the solution for oxidation and reacts with ozone to form 4-acetaminotoluene. The main reaction products are peroxide compounds (71%), and to a lesser extent - the products of oxidation at the methyl group - 4-acetaminobenzilacetat and 4-acetaminobenzilidendiacetat, the total yield of less than 26%. Figure 4, Table. 5, Publ. 8. | |||||
| 541.127: 542.943 .., .., .., .. . . . 6, 6, . 14. | |||||
| 541.127: 542.943 .., .., .., .. ʳ . . . .6, . 6, . 14. | |||||
| UDK 541.127: 542.943 Galstjan G.., Bushuev .S., Galstjan .., Kolbasiuk .. The kinetics and products of the oxidization of aminotoluenes by ozone in the acetic acid. The researches of kinetic conformities to law and mechanism of reactions of the oxidization of aminotoluenes and their acetylated derivatives are conducted in an ice acetic acid. The process of catalytic oxidization of acetaminotoluenes by ozone in the liquid phase is studied in presence salts of transitional metals and their mixtures with the bromide of potassium. Pictures 6, Tables 6, Publ. 14. | |||||
| 546.214 .. . . . , , (). , 2 2. , . . 3. . 9. | |||||
| 546.214 .. . . . , , (). , 2 2. , . .3. .9. | |||||
| UDK 546.214 Zakharova O.I. The investigation of the formic aldehyde catalytic oxidation by ozone in water solutions. The report . The investigation of the process of formic aldehyde catalytic oxidation by ozone in water solution in the presence of transition metal salts have been carried out. It is established that appreciable catalytic activity in this process is shown by the vanadylum sulfate, sulfate and pyrophosphate of manganese (). Most catalytic activity is possessed by the manganese sulfate in presence which it is possible to attain complete oxidation of the formic aldehyde to CO2 and H2O. The obtained experimental data correspond offered the representations about the mechanism of the catalysis including fast ozone reaction with the metal and the reaction of oxidized form of the metal with a formic aldehyde. Fig.3. Lit.9. | |||||
| 541.127: 542.943 .., .., .., . . : . . , . , - . .1, . 1, . 10. | |||||
| 541.127: 542.943 Ѻ .., .., .., . ʳ . ó : . . , . , - . .1, . 1, . 10. | |||||
| UDK 541.127: 542.943 Sedych A.A., Galstjan G.A., Galstjan A.G., Mande Garba. Kinetics and the oxidation mechanism of hydroxytoluols ozone in acetic anhydride in the presence of manganese acetate. Hydroxytoluols co-operate with ozone in two competing directions: on an aromatic ring and methyl group. The parity of products of oxidation depends on ozonization conditions. It is established, that selectivity of oxidation on methyl group considerably raises in the presence of salts of transitive metals. It is proved, that reaction proceeds on the ionic-radical mechanism. A Fig. 1, Tab. 1, Publ. 10. | |||||
| 547.657+547.541.112 .., .., .. 6--5-. 6-. . : , 6--5-. 1, . 2, . 7. | |||||
| 547.657+547.541.112 .., .., .. 6--5-. 6-. ϳ . : , 6--5-. 1, . 2, .7. | |||||
| UDK 547.657+547.541.112 Pogorelova I.P., Andreev P.Yu., Potapenko E.V. Development of methods of synthesis 6-methyluracil-5-sulphochloride. The results of experimental data of sulphochlorination of 6-methyluracil. Select the optimal mode of sulphochlorination. The influence of inorganic oxychlorides and molar ratio of ice:acetic acid in the allocation, the output of 6-methyluracil-5-sulphachloride. Fig 1, Tab. 2 Sour. 7. | |||||
| 542.953.4 .., .. - . , , . . . 3, .1, . 12. | |||||
| 542.953.4 .., .. ʳ . , , . . . 3, .1, . 12. | |||||
| UDK 542.953.4 Demchenko O.A., Belkin D.I. Kinetics and mechanism of reactions of formation of dipentaerythritol and bispentaerythritolformal during condensation of formaldehyde and acetaldehyde in alkaline solutions. Information proving, is expounded, that reason of dependence of output of dipentaerythritol and bispentaerythritolformal the concentration of formaldehyde are reactions formation of hemiacetals of pentaerythritol and formaldehyde. Kinetic descriptions of reactions of formation of dipentaerythritol and bispentaerythritolformal are appraised. Fig. 3, Tabl.1,Sour. 12. | |||||
| 661.546.175.323 .. .., .., .., .. . , . . | |||||
| 661.546.175.323 .., .., .., .., .. . , . . | |||||
| UDK 661.546.175.323 Shevchenko V.Yu. Grin' G.I., Romenskiy A.V., Sozontov V.I., Kolesnikova T.B. Influence of oxygen additional on technology of nitric acid receipt. The article describes and substantiates the use of unclaimed technical oxygen for enrichment of the air used in production of regular nitric acid. It shows the effect of the additional oxygen on the nitric acid production process and determines its threshold quantity. | |||||
| 661.546.175.323 .., .., .., .. , . , . , NO3-N2O4-H2O-HF-H3PO4. . | |||||
| 661.546.175.323 .., .., .., .. , . , 糿. , 䳿 NO3-N2O4-H2O-HF-H3PO4. . | |||||
| UDK 661.546.175.323 Sozontov V.I., Kazakov V.V., Romenskiy A.V., Suvorin A.V. Thermodynamics analysis of fluorine hydrogen extraction process from solutions of the concentrated nitric acid and oxides of nitrogen, containedof ortofosfornuyu acid. Based on theoretical studies it was demonstrated that recovery and recycling of solutions of concentrated nitric acid and nitrogen oxides containing corrosion inhibitors was possible. The thermodynamic constants and the concentration of components in a chemical equilibrium of possible reactions proceeding in the interaction of aluminium and calcium nitrates in HNO3-N2O4-H2O-HF-H3PO4 system were calculated. Conditions for almost complete recovery of hydrogen fluoride from the solutions were determined. | |||||
| 539.192 .. n2 n2o (iv) N2O N2 (IV) , NO2 N2O NO, N2, O2 . NO, . , NO2(2'') . | |||||
| 539.192 .. n2 n2o (iv) N2O N2 (IV) , NO2 N2O NO, N2, O2 . ³ NO, . , NO2(2'') . | |||||
| UDK 539.192 Kravchenko I.V. Oxidation of N2 and N2O nitric oxide (IV) By researches of oxidation N2O and N2 by nitrogen oxide (IV) it is shown that in the course of photochemical oxidation N2O to NO, N2, O2 nitrogen dioxide is not lost. It turns into NO from which it is newly regenerated. Established that the third excited state of nitrogen dioxide NO2(2A'') does not oxidation of molecular nitrogen | |||||
| 678.074:678.01 .., . . . ( ) , , . . . 3, 4. | |||||
| 678.074:678.01 .., .. . ( ) , , . . . 3, 4. | |||||
| UDK 678.074:678.01 Ersh V.P., rvchn .A. Research of kinetics of polikondensation in the synthesis of sulfocontaining oligoester. Influence of temperature is investigational on speed of reaction of synthesis of sulfocontaining oligoester on the basis of mixtures of carbokcilcontaining monomers (maleinic anhydride and sebacic acid) and hidrokcikcontaining monomers (diglycol and sodium salt of propanechlorhydrinsulfoacid). The quantitative values of speed of polyreaction are found at a few temperatures. Table. 3, Sources 4. | |||||
| 678.074:678.01 .., .. . , . . 4, 5. | |||||
| 678.074:678.01 .., .. ʳ . , . . 4, 5. | |||||
| UDK 678.074:678.01 Myakuhina V.T., Komarova O.A. The kinetics of the synthesis of sulfocontaining olygoesters on the base of dicarbonic acids of different structure. The kinetic researches of the fusion synthesis of the new sulfocontaining oligoester on the base of diethylenglikoly, sebacinic or adipinic acids and sodium salt of propanechlorhydrinsulfoacid were carried out with the purpose of comparison of reactionary ability of type of the dicarbonic acid with the different amount of methylene groups and its influence on polikondensation kinetics. Tablas. 4, Sources 5. | |||||
| 678.074:678.01 .., .. . , , . . . 2, 4. | |||||
| 678.074:678.01 .., .. . , . . . 2, 4. | |||||
| UDK 678.074:678.01 Sharun E.P., Sakson V.V. Catalysis in the synthesis of sulfocontaining olygoesters. The catalizator influence on the reaction speed of synthesis of the sulfocontaining olygoesters on the base of diethyleneglycole, maleinic anhydride, sebacinic acid and sodium salt of the propanechlorhydrinsulfoacid was investigated. The quantity values of the polycondensation speed in the catalizator present at the two temperatures were determined. Tables 2, Sources 4. | |||||
| 628.336.515:658.567 .., .., .., .., .. , . , || || | || || || || || | . ||| - 53, || . | |||||
| 628.336.515:658.567 .., .., .., .., .. , . , - . - 53, . | |||||
| UDK 628.336.515:658.567 Ostrovka V.I., Ruban E.V., Chsnvskj .S., Moroz V.A., Popov E.V. Usage of sndustrial sewage containing aluminium salts as a coagulant in finish purification of sewage. In order to expand raw resources of coagulants in purification system of un industrial sewage and to solve the problem of utilizing aluminium containing sewage of some dyes industry manufactures, the possibility of using this industrial sewage in finish purification of biologically purified sewage of amline dyes enterprises has been studied. Alyuminium containting sewage of manufacturing such dyes as vat bright jellow GH and vat brown 5Z as the most concentrated ones according to their aluminium salt content has been inwestigated in this paper. | |||||
| 541.64:542.954 .., .. . , 1 3- . , . . 3, . 1, . 5. | |||||
| 541.64:542.954 .., .. ' . , 1 3- . , . . 3, . 1, 5. | |||||
| UDK 541.64:542.954 Kondratov S.A., Oleynik V.V. Computer modelling of the equilibrium polycondensation. By the method of raster visualization it is shown that the system of the equations for the description of equilibrium polycondensation depending on conditions has from 1 to 3 roots. The criterion of the search of the real root which have a physical sense was developed. Fig. 3, Tab. 1, Sources 5. | |||||
| 622.769.2:621.8.036 .., .. - . , . - , ( () (2)) . | |||||
| 622.769.2:621.8.036 ̳ .., .. - 㳿 . , 㳿. - , ( () (2)) . | |||||
| UDK 622.769.2:621.8.036 Mlots'kiy V.V., Ostapenko V.O. Organka zhivo prirodi - nevicherpne vdponovlyuvane dzherelo energ that two person vodnevo energetiki. The problem of energil of humanity, which is investigation of narrow-mindedness of supplies of fossil energy sources is examined. Complex of new ecological -energetik technologies provides utilization of domestic organic wastes not simply, but ecological clean decomposition on primitive power mediums (coal () and hydrogen (N2)) - dear organic of wild-life and molecular connections of hydrogen. | |||||
| 665.6+66.07 .. . . . | |||||
| 665.6+66.07 .. . . . | |||||
| UDK 665.6+66.07 Mamedov B.B. Coking proces - should be prepared increasing depth processing of oil in Ukraine. The article discussed and the necessity to use the coking process in petroleum refining and coking industry of Ukraine. The possibility of optimizing the production of coke. | |||||
| 678.074.02 .., .C. . . . . . 4. 2. | |||||
| 678.074.02 .., .C. . . . . . 4. 2. | |||||
| UDK 678.074.02 Ppnk G.V., Shishina .S. Chalk filled polypropylene. The result of receipting of polypropylene filled of chalk are presented in this project. The influence of amount of files on property polypropylene wares had been researched. The uniform structure of polypropylene composition for getting wares with f good exploit propertys had been dthined. Table.4. Sources 2. | |||||
| 66.094.524.55.097.135 .., .., .. . , . . 11. : , , , , . | |||||
| 66.094.524.55.097.135 .., .., .. . 㳿 , . . 11. : , , , , . | |||||
| UDK 66.094.524.55.097.135 Starichenko L., Popov E., Isak A. To the question of sulfoalkylation of phenol and his derivatives. In article are considered the problems of technology of sulphonating organic compounds, offered and studied alternative reaction of sulfoalkylation in the conditions of phase transfeer catalysis. Ref. 11. Keywords: sulfoalkylation, sulfomethylation, bisulfite derivative aldehyde, phenol, phase transfeer catalysis. | |||||
| 541.128.24 .., .., .., .. . , , . | |||||
| 541.128.24 .., .., .., .. ' . , ', . | |||||
| UDK 541.128.24 Tyulpinov D.., Tyulpinov .D., Suvorin A.V., Zaika R.G. Theoretical aspects of determination temperature extinguishing of flame by the layer catalyst. The method of determination of temperature of the fluidized layer of catalyst, which extinguishing of flame is at, is offered, by recommendations of catalysts. | |||||
| 66.097.3 .. -. 2 , . , . 2, , , . | |||||
| 66.097.3 .. -. 2 , . , 2 . 2, , , . | |||||
| 66.097.3 Ovsienko O. Features of Industrial Putting into Operation Methanol Catalyst SNM-U. The phenomenon of short-term CO2 concentration rise in a gas phase during industrial startings of just activated methanol synthesis catalysts and at restarting after outages has been revealed. Investigation showed the catalyst not to be a CO2 source. The short-term CO2 concentration increase is probably caused by changing the rate of reactions of methanol formation and carbon oxide conversion because of pressure and temperature variations at starting operations. | |||||
| 544.72.02 .., .. Al2O3 . . | |||||
| 544.72.02 .., .. Al2O3 . || || . | |||||
| UDK 544.72.02 Goncharov V.V., Solov'ev G.I. Synthesis of Al2O3 on the surface of block substrates for catalysts from stainless steel. In the article comparative description of three methods|heliochrome| of forming of support| of oxide of aluminum|aluminon| on-the-spot sectional cellular|honeycomb| transmitters|carrier| for catalysts|catalist| on the base of stainless steel is resulted | |||||
| 66.09 .., .., .. . 650 7470 . . .2. .3. . 4. | |||||
| 66.09 .., .., .. . 650 7470 . . .2. .3. . 4. | |||||
UD 66.09
Tarasov V.Yu., Zaika R.G., Nechistyak K.J.
The research and development of the timing device for the
: 2017-02-25; !; : 421 | : :  | 1247 -  |
: 0.04 .