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, . , 100 % . , , .
|
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. 7.1.
7.1.
/ | , / (/) | , / | |
1 (1) | 1/ | ||
1 (1) | 1/ | ||
........ | ........ | ..... |
, . .
7.4. . 10000 /. 0,7; ( ) 0,8. - 40 % .
HCOOH:CO2:CO:CH4=1,8:1,6:0,1:0,3.
341 (- ) .
: 550-600 , :
CH3OH+1/2O2=CH2O+H2O, (1)
CH3OH=CH2O+H2, (2)
CH3OH=CO+2H2, (3)
CH3OH+H2=CH4+H2O, (4)
CH3OH+O2=HCOOH+H2O, (5)
CH3OH+1,5O2=CO2+2H2O. 6)
H2+1/2O2=H2O , (2) (1), .
80 % : =2: 1 , (3).
20-21 % , 36-38 % , CO2, CH4, CH3OH, HCOOH . - 60 , . 10-12 % , , . : 30; 32; 16.
100001000/341/24=1220 / 1220/30=40,7 /.
(1) (2) 1 1 , , 70 % ,
|
|
40,7/0,7=58,12 / 58,1232=1860 /.
.
58,1222,4=1300 3/.
- 1300/0,4=3250 3/.
3250-1300=1950 3/, :
19500,21=410 3/ 41032/22,4=586 /;
19500,79=1540 3/ 154028/22,4=1920 /.
, (3)-(6). 80 %
58,12(0,8-0,7)=5,81 /.
58,120,2=11,6 / 11,632=372 /.
1,8+1,6+0,1+0,3=3,8.
:
(HCOOH) 5,81,8/3,8=2,75 / 2,7546=126,5 /.
(2) 5,81,6/3,8=2,45 / 2,4544=108,0 /.
() 5,80,1/3,8=0,158 / 0,15828=4,3 /.
(4) 5,80,3/3,8=0,459 / 0,45916=7,3 /.
. :
586 /;
186016/32=930 /. :586+930=1516 /.
:
122016/30=650 /;
126,532/46=88 /;
2 10832/44=78,6 /;
4,316/28=2,45 /;
37216/32=186 /.
1005 /.
, 1516-1005=509 /, (1), (4), (5) (6). 50918/16=572 /.
7.2.
/ | % ( ) | / | % ( ) | ||
- : | 42,6 13,4 44,0 | 2 | 1220,0 372,0 572,0 126,5 108,0 4,3 7,3 34,1 1920,0 1,8 | 27,89 8,58 13,12 2,90 2,47 0,09 0,16 0,78 43,97 0,04 | |
: | 100,0 | : | 4366,0 | 100,00 |
18604/32=233 /.
:
2 122022/30=81,5 /;
126,52/46=5,5 /;
4 7,34/16=1,82 /;
2 5722/18=63,6 /;
3724/32=46,5 /.
198,9 /.
233-198,9=34,1 /.
. 7.2 .