, , , . I (), , (/) I/zF, . , V (3), VdC2/dτ ( C2 ) :
= 1/zFV.
I i = I/S ( S , 2):
, .
:
1 .
, , , . - . , *.
1. , . . .
:
δ , . . ,
:
ln 2 = Κτ + const
τ = 0
const = ln
:
ln 2 = ln Κτ
(, . . . . , . 14.16), . , . . . , , , , , (12 16 /), , .
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* , , . .
. 14.16. .
2. , .
S = K1/( C2)
dC2/dτ = (DS/δV)C2
ln C2 + C2 = K1τ + const
, τ = 0 2 = .
const = ln +
, . . , (. 14.17).
3. , - .
-
. 14.17. :
; .
. 14.18. .
h , .
, . - (D1/δ)( C1). C1 , ( C1) = const. ( C2).
dC2/dτ = K/( C2) dC2 C2dC2 = Kdτ
:
C2 ½C22 = Kτ + const
τ = 0 2 = . , const = ½ 2 2 + + C22 = 2Kτ . . . . . 14.18.
4. . . , . , . , , . , .
Ik = Ia
Ik = ikSk; Ia = iaSa
:
; α* α* .
:
I = Ia
I , :
K . . . . . .
. p = 1 ( ), 2. αk* = 0, . . , , . (α* = 0,5), (α* = 1,5), 3/4, = 1, 3/2, = 2, . . .
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. . , , . . (. 14.19, ). , . , . , lg i lg C . 14. 19, .
. 14.19, , 0,7. , ,
. 14.19. :
i ; .
, , .