X.
10.1. :
3111-113;
.
(2,52 ) S / D. S / D = 1, .. .
D =100 
= 92,91 ;
: S = 93 ;
D = 93 .
ε = 10,1.
V = S ∙ nN / 3104 = 934500/ 3104 = 13,95 /.
10.3. ().
n min = 875 min ¹ ;
n = 2250 min ¹ ;
nN = 4500 min ¹ ;
n max = 4950 min ¹ .
.
92, 92 .
,
ε = 10,1 92 , :
C = 0,855; H = 0,145; m = 115 /.
u = 33,91C +125H 10,89(O S) 2,51(9H + W),
W = 0; O = 0; S = 0.
.
:
u = 33,91 0,855 + 125,6 0,145 2,51(9 0,145 + 0) = 43,93 /
.
) .
L o = (1/0,208)(C/12+H/4 O/32),
L o = (1/0,208)(0,85/12 + 0,145/4) = 0,517 / .
)
l o = (1/0,23)(8/3C + 8H 0),
l o = (1/0,23)(8/30,855+80,145) = 14,957 / .
.
α = L g/ L o = l g / l o,
L g, l g ; L o, l o () .
α
n min = α = 0,96; n = α = 1; nN = α =1; n max = α = 0,98.
.
M 1 = α L o + 1/ m ,
α , m = 115 / .
M 1 (n min) = 0,960,517+1/115 = 0,5049 / ;
M 1(n ) = 10,517 +1/115 = 0,52552 / ;
1(nN ) = 10,517+1/115 = 0,52552 / ;
M 1(n max) = 0,840,517+1/115 = 0,51519 / .
.
K = 0,47 ( K = 0,45 0,5),
K , (H2) (CO) .
|
|
|
M 2= (C/12) 2((1 α)/(1 + K))0,208 L ; M = 21 α/1 + K 0,208 L o;
M H2O = (H/2) 2 K ((1 α)/(1+ K))0,208 L o; M H2= 2 K 1 α/1 + K 0,208 L o;
M N2= 0,792α L o;
M 2(n min) = (0,855/12) 2[(1 0,96)/(1 + 0,47)]0,2080,517 = 0,0654 CO2 / ;
M (n min) = 2 [(1 0,96)/(1 + 0,47)]0,2080,517 = 0,00585 CO / ;
M H2O (n min) = (0,145/2) 20,47[(1 0,96)/(1 + 0,47)]0,2080,517 = 0,07
H2O / ;
M H2(n min) = 20,47[(1 0,96)/(1 + 0,47)]0,2080,517 = 0,00275 H2 / ;
M N2(n min) = 0,7920,960,517 = 0,39295 N2 / .
M 2(n) = (0,855/12) 2[(1 1)/(1 + 0,47)]0,2080,517 = 0,07125 CO2 / ;
M (n) = 2[(1 1)/(1 + 0,47)]0,2080,517 = 0 CO / ;
M H2O (n) = (0,145/2) 20,47[(1 1)/(1 + 0,47)]0,2080,517 = 0,073 H2O / ;
M H2(n) = 20,47[(1 1)/(1 + 0,47)]0,2080,517 = 0 H2 / ;
M N2(n) = 0,79210,517 = 0,40933 N2 / .
M 2(nN) = (0,855/12) 2[(1 1)/(1 + 0,5)]0,2080,517 = 0,07125 CO2 / ;
M (nN) = 2[(1 1)/(1 + 0,47)]0,2080,517 = 0 CO / ;
M H2O (nN) = (0,145/2) 20,47[(1 1)/(1 + 0,47)]0,2080,517 = 0,073 H2O / ;
M H2(nN) = 20,47[(1 1)/(1 + 0,47)]0,2080,517 = 0 H2 / ;
M N2(nN) = 0,79210,517 = 0,40114 N2 / .
M 2(n max) = (0,855/12) 2[(1 0,98)/(1 + 0,5)]0,2080,517 = 0,06832
CO2 / ;
M (n max) = 2[(1 0,98)/(1 + 0,47)]0,2080,517 = 0,00293 CO / ;
M H2O (n max) = (0,145/2) 20,47[(1 0,98)/(1 + 0,47)]0,2080,517 = 0,071
H2O / ;
M H2(n max) = 20,47[(1 0,98)/(1 + 0,47)]0,2080,517 = 0,001375 H2 /
;
M N2(n max) = 0,7920,980,517 = 0,40114 N2 / .
.
M 2 = M 2+ M + M H2O + M H2+ M N2,
M 2 (n min) =0,0654 + 0,00585034 + 0,06975 + 0,00275 + 0,39295 = 0,53670385 / ;
M 2(n ) = 0,07125 + 0 + 0,0725 + 0 + 0,40933 = 0,55307692 / ;
M 2(nN) = 0,07125 + 0 + 0,0725 + 0 + 0,40933 = 0,55307692 / ;
M 2(n max) = 0,06832 + 0,00292517 + 0,07113 + 0,00137 + 0,40114 = 0,54489038 / .
10.1
.
| n min | n | nN | n max | ||
| n, min 1 | |||||
| α | 0,96 | 0,98 | |||
| M 1 | 0,50485 | 0,52552 | 0,52552 | 0,51519 | |
| M 2 | 0,0654 | 0,07125 | 0,07125 | 0,06832483 | |
| M | 0,00585 | 0,00292517 | |||
| M H2O | 0,06975 | 0,0725 | 0,0725 | 0,071125 | |
| M H2 | 0,00275 | 0,001375 | |||
| M N2 | 0,392954 | 0,409327 | 0,409327 | 0,40114 | |
| M 2 | 0,536704 | 0,55308 | 0,55308 | 0,54489 |
|
|
|
.
.
P o = 0,1 ;
T o = 293 K ;
