, .4.1.2
4.1.2
| T,K | <V> / | |||||||||||
| N2 | 515.91 | 516.12 | 515.73 | 516.20 | 516.82 | 515.5 | 514.95 | 515.32 | 516.2 | 515.28 | ||
| CO | 511.20 | 511.52 | 510.88 | 510.48 | 511.20 | 510.43 | 510.50 | 511.15 | 512.0 | 510.45 | ||
| CO2 | 375.50 | 374.90 | 374.82 | 375.41 | 376.02 | 374.82 | 373.88 | 374.32 | 375.12 | 374.80 | ||
| O2 | 424.9 | 425.3 | 425.6 | 424.7 | 424.7 | 424.8 | 425.1 | 424.9 | 425.3 | 425.5 | ||
| He | 1248.1 | 1247.9 | 1246.0 | 1248.2 | 1247.5 | 1249.1 | 1248.1 | 1246.9 | 1247.1 | 1247.9 | ||
| CH4 | 683.30 | 684.12 | 683.40 | 684.0 | 682.98 | 683.65 | 684.12 | 682.80 | 683.65 | 683.45 | ||
| NH3 | 684.92 | 685.10 | 684.50 | 684.42 | 685.70 | 684.95 | 684.95 | 683.87 | 684.70 | 684.65 | ||
| H2 | 1699.6 | 1698.3 | 1699.8 | 1699.7 | 1698.9 | 1697.9 | 1699.1 | 1699.2 | 1698.7 | 1698.7 | ||
| N2 | 515.91 | 516.12 | 515.73 | 516.20 | 516.82 | 515.5 | 514.95 | 515.32 | 516.20 | 515.28 |
1 :
= = <X>; <X> = 
(4.1.7)
N
i
2 DXi
.
DXi = |Xi | (4.1.8)
3 <DXi >
<DXi > = (4.1.9)
4 e%
:
e = 
e = 
(4.1.10)
5 :
= <> ¹ <DXi > (4.1.11)
4.1.3
| T, | V | < V > | D Vi | <D Vi > | e% | ||
2
1
1 2 3
2 DXi2.
3
d = 
(4.1.12)
4 3
4.1.4
| T, | V | < V > | DV i | DV i 
| d% | ||
|
|
|
3.
4.1.1
1 4.1.3 4.1.4
2 :
DX = 0,674∙ d, (4.1.13)
0.6745
1 1.4.4
4.1.5
| T, | V | < V > | DV i | DV i
| d% | DX | ||
1. , 11-4 4.1.2 , 22-3 ( Dνi2, 2 2
3.
d = , (4.1.14)
4.1.5
4.
DV = 0,6745 ∙ d, (4.1.15)
0.6745 , 4
1. .
2. .
3. , , , ?
4. ?
4.1.8 :
2
:
: ( ) 2 . , , , , , ( )
