.
,
2 () + () 2()
:
.
, , , (. ),
Dn - .
,
.
. | (4.21) |
(4.21) , , .
( ), , , .
, , , , .
4.14.3. .
. : (, , ) . .
, , , ( ), .
.
H2() + I2() 2 HI()
( )
.
, , , .. , ( )
= [H2] [I2], > ,
. , .
, . , , , .
, :
= [HI] 2, > ,
.
( ) , ( ) .
.
( ) , .. , .
|
|
( ) , .. , .
,
CO() + Cl2() COCl2(),
?
2 , 1 . . , , .
, , ( ) .
H2() + I2() 2 HI()
. , .
.
, | (4.22) |
D <0 Kp , () .
,
N2() + 3H2() 2NH3(),
(D <0), (4.22) . . Kp ∆S . .
(D >0) Kp , () .
,
N2O4 () 2 NO2 (), D Ͱ =57,4
(D >0), .. . , (4.22) . ∆S . .
D , , .
, , .. .
.