, , , Ze (, +, Li2+), .
, , . (208.1) mev2/r = Ze2/(4pe0r2), , (210.1), n- :
(212.1)
n = 1, 2, 3,.... (212.1) , .
(Z = 1) n = 1, (),
(212.2)
. , , . , .
(mev2/2) (-Ze2/(4pe0r):
(, ; . (208.1)). n- (212.1), , :
(212.3)
, .
(212.3) , , n. n (212.3), , . n = 1 () ; n > 1 . , , () ; .
n , (Z= 1), (212.3), , . 294. n , n = ¥. , , (E1 = 13,55 ) n = 1. (E¥ = 0) n = ¥. , E¥ = 0 ( ). (. (210.2)), (Z= 1) n m
(212.4)
R , , (. 209). (212.3) .
|
|
, , (212.4) m =1 n =2, 3, 4,..., , (. 209) (n =2, 3, 4,...) (m = 1). , m = 2, 3, 4, 5, 6 n , , , ( . 294), 209. , , , , , .
. 294
, . . ( n = 1), ( ).
. ( , , ). , : ? , .
27.1. ( ). [Emax =13,2 , Emin = 10,2 ]
27.2. , . [364 ]
27.3. , , . [pm=enℏ/(2m) = 1,8×10-23 ×3]
27.4. , (n = 2) l = 1.212×10-7 . [DL=ℏ=1.05×10-34 ×]
27.5. . [13,6 ]
27.6. , Ei = 13,6 , . [12,1 ]
27.7. , Ei =13,6 , - , . [10,2 ]
28