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Production composite moulding




Processes

There are many fibreglass reinforced plastic moulding

processes available to the designer. Each

process has its own characteristics, as well as its

own limitations as to part size, shape, production

rate, compatible reinforcements, and suitable resin

Reinforced composite materials 547

limitations. This means that the vehicle body structures

can be moulded in much fewer sections, minimizing

panel assembly times and costs. Lotus

mould their complete bodyshell in a few pieces,

each of which has an integral moulded structure.

This structure uses isophthalic polyester resin in

conjunction with continuous filament mat. In addition,

woven and unidirectional glass reinforcements

are used in areas where more specific loadings are

required. Kevlar aramid materials are also included

where particularly high strengths are needed.

The VARI tooling, which can be either metal

faced or constructed entirely from composite

materials, is designed so that each tool becomes its

own press. The pressure is created by vacuum

which draws the tools together and holds the male

and female throughout the moulding cycle.

Therefore no mechanical clamping mechanisms

are involved. After closing the tools the resin is

injected using a machine which dispenses precise

quantities of catalysed materials. After the curing

cycle the vacuum is reversed and the tools open,

releasing the moulded panel or body section.

16.7 Designing reinforced composite

materials for strength

The ability to design and fabricate large structures

as a whole, rather than as an assembly of components,

is one of the chief advantages that glass

resin laminates bring to the designer. This is supported

by the ease of modifying the material thickness

at specific locations and, taking advantage of

the properties of the various types of reinforcement,

by building in extra strength at any point and

in any direction (Figure 16.24). The skill of the

operator is an important factor.

Strength of glass fibre reinforced plastic laminates

in any direction is dependent on the orientation of

fibre reinforcement to that direction (Figure 16.25).

When chopped strand mat is used, its random fibre

arrangement can be expected to give roughly equal

mechanical properties in all planes; however, maximum

strength will in practice be parallel to the

plane of the laminate. Plain woven roving gives

optimum mechanical properties at right angles, while

unidirectional roving mat shows highest strength

along the roving; as the roving is continuous and

uncrimped, this last type will be stronger than other

types of reinforcement.

There is still an unfortunate tendency on the part

of designers to use a traditional design, known to

be satisfactory for wood or metal, for reinforced

plastics which have, of course, completely different

properties and processing characteristics

(Tables 16.3 and 16.4). This may give glass fibre

reinforced plastic mouldings of incorrect shape,

since although conventional materials are well

suited to straight lines and flat surfaces, the properties

of glass fibre reinforced plastic components

are improved by the introduction of curvature, and

if possible double curvature, to the design. The

specific strength (tensile strength weight ratio) of

glass-polyester laminates is high, but rigidity tends

to be on the low side. It may therefore be necessary

to design for additional rigidity rather than for

optimum tensile strength. This can be effected by

various means, of which increased overall moulding

thickness is perhaps the least desirable as it is

wasteful and may well add unnecessary weight.

The use of simple or compound curves in the

design may be the answer, or perhaps local corrugations

can be introduced as in metal designs;

these can often be incorporated into the overall

styling, especially in vehicle bodies. Localized

thickening, particularly towards the edges of a

panel, will contribute usefully to the stiffness of

the moulding. A common practice to achieve extra

rigidity is the integral moulding of ribs into the

reverse face of the laminate. These ribs, which are

often used in large boat hulls, can be solid or hollow;

for solid ribs a permanent core of glass fibre,

wood or plastic foam can be laminated in, while

hollow ribs are achieved by use of removable tube

or simple former of cardboard or similar material

(see Figure 16.14).

Large panels can be made considerably more

rigid by the employment of a sandwich form of

construction, whereby two layers of glass fibre

reinforced plastic are separated by a thick but relatively

weak lightweight material. The benefit here

derives from the fact that stiffness is a direct function

of thickness. Other advantages of this method

are increased heat and sound insulation. Stress

analysis is usually based upon the tensile strength at

which crazing of the resin matrix occurs. This corresponds

to the yield point of conventional materials.

It is usual to allow a safety factor of between

1:3 and 3:5, depending upon the conditions of service.

Frequently the stressing of a moulding is so

548 Repair of Vehicle Bodies

Reinforced composite materials 549

Figure 16.22 Composite moulding processes (Owens-Corning Fiberglas)

(a) Hand lay-up is a low-to-medium volume moulding method suitable for making boats, tanks, housings and

building panels and other large parts requiring high strength. The process provides only one finished surface.

(b) Spray-up is a low-to-medium volume moulding method similar to hand lay-up in its suitability for making

boats, tanks, tub/showers and other medium to large size shapes. Greater shape complexity is possible with

spray-up than with hand lay-up.

(c) Resin transfer moulding (RTM) is suitable for medium-volume production and may be regarded as an

intermediate process between spray-up and faster compression moulding methods using SMC and BMC.

RTM provides two finished surfaces. The reinforcement is placed in the bottom half of the mould. The mould

is then closed and clamped, and catalysed resin is pumped in under pressure until the mould is filled.

Moulds are usually made of reinforced plastics.

(d) Compression moulding is a high-volume, high-pressure process suitable for moulding complex,

high-strength fibreglass reinforced plastic parts using sheet moulding compound, bulk moulding

compound or preforms. Fairly large parts can be moulded in medium to high volumes with excellent

surface finish.

(e) Injection moulding is the highest volume method of any of the fibreglass reinforced plastic processes using

single or multi-cavity moulds to produce large volumes of complex parts at high production rates. Advanced

fibreglass technology makes it possible to injection mould glass reinforced thermoplastics that provide a

wider variety of mechanical, chemical, electrical and thermal properties than previously available.

(f) Thermoset moulding compounds are injection moulded with a low-temperature injection screw/plunger and

chamber, and a high temperature mould. This cures the thermoset material under heat and pressure.

Injection moulding of thermoset resins offers the capability to produce high volumes of very complex parts

with good mechanical properties and impact strengths.

(g) Pultrusion is a continuous process for the manufacture of products having a constant cross-section, such as

rod stock, structural shapes, beams, channels, pipe, tubing and fishing rods.

(h) RRIM is emerging as a leading process. RRIM provides low-cost tooling, low-pressure moulding and design

flexibility to accommodate inserts or encapsulations of structural supports.

complex that it defeats analysis. In such cases it

may be necessary to base the design upon the

known performance of a similar structure and to

produce a prototype moulding for testing under

service conditions. Where metal inserts are to be

incorporated in the moulding, allowance should be

made in the design of the joint for the greatly differing

yields of the two materials under similar

loading. A wider insert will result in lower stress

per inch at the load transfer point. The stress in the

resin laminate can be taken up to a point where

strain in both materials is similar by thickening

the laminate where it approaches and surrounds the

metal insert. Ideally the base of the insert should be

about four times as wide as it is long.

It is better to achieve load transfer by adhesion

rather than by mechanical interlocking; mechanical

methods are satisfactory, however, if only small

loads are involved. Joining of two glass fibre reinforced

plastic componenets to each other can be

effected by adhesive or mechanical means, or by a

combination of both. In adhesive joint design the

bonding area should be as large as possible. For ordinary

butt or scarf joints, extra reinforcement should

be provided by lamination of extra layers of resin

and glass over the joint on both sides; in general it is

better to use overlapping joints (Figure 16.26).

Exposure of glass fibre by roughening in each case

will enhance bond strength. Cured laminates are

commonly bonded by means of epoxy-type adhesives.

A polyester resin adhesive may be used, but

here it is necessary to ensure that the adhesive films

are thick enough to avoid problems of undercure.

This can be done by including a single sheet of

glass cloth or mat with open texture in the joint.

Most kinds of mechanical fastener (nuts and bolts,

(Facing page)

550 Repair of Vehicle Bodies

Figure 16.23 Cold press process: (a) 50 tonne hydraulic press (b) Kirksite metal mould (c) moulding

(d) continuous filament glass (e) polyester surface finish (Reliant Motor PLC)

self-tapping screws, rivets and others) can usually be

employed without any trouble, provided the load is

spread by means of large heads and/or large washers.

To prevent laminate crushing it is a good plan to use

spacers for bolted connections. Provided the extent

of the bonded area is taken into account, and thorough

cleaning and roughening are carried out, there

is no reason why drilled and tapped metal plates, or

special tapped inserts, should not be laminated into

the moulding or on the reverse side.

Composite theory

In its most basic form a composite material is one

which is composed of two elements working

together to produce material properties that are different

to the properties of those elements on their

own. In practice, most composites consist of a bulk

material called the matrix, and a reinforcement

material of some kind which increases the strength

and stiffness of the matrix.

Polymer matrix composites (PMC) is the type of

composites used in modern vehicle bodywork.

This type of composite is also known as Fibre reinforced

polymers (or plastics) (FRP). The matrix is

a polymer-based resin and the reinforcement material

is a fibrous material such as glass, carbon or

aramid. Frequently, a combination of reinforcement

materials is used.

The reinforcement materials have high tensile

strength, but are easily chaffed and will break if

folded. The polymer matrix holds the fibres in

place so that they are in their strongest position and

protects them from damage. The properties of the

composite are thus determined by:

• The properties of the fibre.

• The properties of the resin.

Reinforced composite materials 551

• The ratio of fibre to resin in the composite –

fibre volume fraction (FVF).

• The geometry and orientation of the fibres in

the composite.

Resin

The choice of resins depends on a number of characteristics,

namely:

• Adhesive properties – in relation to the type of

fibres being used, and if metal inserts are to be

used such as for body fitting.

• Mechanical properties – particularly tensile

strength and stiffness.

• Micro-cracking resistance – stress and age

hardening causes the material to crack, the

micro-cracks reduce the material strength and

eventually lead to failure.

• Fatigue resistance – composites tend to give

better fatigue resistance than most metals.

• Degradation from water ingress – all laminates

permit very low quantities of water to pass

through in a vapour form. If the laminate is wet

for a long period, the water solution inside the

laminate will draw in more water through the

osmosis process.

• Curing properties – the curing process alters the

properties of the material. Generally oven curing

at between 80 °C and 180 °C will increase

the tensile strength by up to 30%.

• Cost – the different materials cost different

prices.

The main types of resins are polyesters,

vinylesters, epoxies, phenolics, cyanate esters, silicones,

polyurethanes, bismaleides (BMI) and

polyamides. The first three are the ones mainly

used for vehicle body work as they are reasonably

priced (Table 16.5). Cyanates, BMI and polyamides

cost about 10 times the price of the others.

Reinforcing fibres

The mechanical properties of the composite material

are usually dominated by the contribution of

the reinforcing fibres. The four main factors which

govern this contribution are:

1 The basic mechanical properties of the fibre.

2 The surface interaction of the fibre and the

resin – called the interface.

3 The amount of fibre in the composite – FVF.

4 The orientation of the fibres.

The three main reinforcing fibres used in vehicles

are: glass, carbon and aramid. In addition, the following

are used for non-body purposes: polyester,

polyethylene, quartz, boron, ceramic and natural

fibres such as jute and sisal.

Glass is discussed separately in Section 16.4

Aramid Aramid fibre is a man-made organic

polymer, an aromatic polyamide, produced by

spinning fibre from a liquid chemical blend.

The bright golden yellow fibres have high strength

and low density giving a high specific strength.

Aramid has good impact resistance. Aramid is better

known by its Dupont trade name Kevlar.

Carbon Carbon fibre is produced by the controlled

oxidation, carbonization and graphitization

of carbon-rich organic materials – referred to as

precursors – which are in fibre form. The most

common precursor is polyacrylonitrile (PAN);

pitch and cellulose are also used (Table 16.6).





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