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,

 

- ( ) ( f - formation) , 101,325 (1 ) 298 . 298 .

[ /(×] :

= + b + '/T 2 = + b + T 2

a =1 +, .

 

  / / = f (T) , K  
  a b × 103 ' × 10-5  
 
  Ag (.) 0 42.55   25.44 23.97 5.27 0.25 2731234
  1 (.)   28.33   24.35 20.67 12.38 273932
  As (ep)   35.61   24.74 23.28 5.74 298800
  Au (.)   47.40   25.36 23.68 5.19 2981336
  B (.)   5.86   11.09 16.78 9.04 7.49 2981700
  Ba-a   60.67   28.28 22.26 13.81 298643
  B-b = 0.63 10.46 29.29 643983
  Be (.)   9.54   16.44 19.16 8.87 4.77 2981556
  Bi (.)   56.90   26.02 18.79 22.59 298544.5
  Br (.) 111.88 174.90 82.44 20.79 19.98 1.34 0.36 2981000
                    18.33 3.88 0.84 10002500
                              106)    
  Br- (.) 218.87 163.39 238.67 20.79 20.79 20 000 K
  Br2 (.)   152.21   75.69 75.69 298332
  Br2 (.) 30.91 245.37 3.14 36.07 37.32 0.50 1.26 2981600
  () 1.83 2.37 2.83 6.11 9.12 13.22 6.19 2981200
  ()   5.74   8.54 16.86 4.77 8.54 2982500
  (.) 716.67 157.99 671.28 20.84 20.80 2981600
  2 (.) 830.86 199.31 774.86 43.21 30.67 3.97 10.19 2982000
  -a Q 41.63   26.36 22.22 13.93 273713
  Cd-a   51.76   25.94 22.22 12.30 273594
  1 (.) 121.34 165.08 105.35 21.84 23.14 0.67 0.96 2982000
  1-(.) 233.63 153.25 239.86 20.79 20.79 20 000 K  
  12(.)   222.98   33.93 37.03 0.67 2.85 2983000
  Co-a   30.04   24.81 19.83 16.75   298700
  r (.)   23.64   23.35 24.43 9.87   3.68 2982000
  Cs (.)   84.35   31.38 31.38 273301.8
  u (.)   33.14   24.43 22.64 6.28   2981357
  D () 221.67 123.24 206.52 20.79 20.79 20 000 K
  / / Ke pe = f (T) Temepp ep, K  
  a b × 103 ' × 10-5  
  D2 (.)   144.86   29.20 28.58 0.88 1.96 ( ×106) 2981500
  F (.) 79.38 158.64 62.30 22.75 23.70 3.21 298500
            21.08 0.10 2.67 5003000
  F-(.) 259.68 145.47 266.61 20.79 20.79 20000 K
  F2 (.)   202.67   31.30 34.56 2.51 3.51 2982000  
  Fe--a   27.15   24.98 17.24 24.77 298700
              159.80 181.00 332.36 7001000
  Ga (.)   41.09   26.07 26.07 298302.9
  Ge (.)     31.09   23.35 25.02 3.43 2.34 2981210
  H (.) 217.98 114.60 203.28 20.79 20.79 20 000 K
  H+ (.) 1536.21 108.84 1517.00 20.79 20.79 20 000 K
  H- (.) 139.03 108.85 132.26 20.79 20.79 20 000 K
  H2 (.)   130.52   28.83 27.28 3.26 0.50 2983000
  Hg (.)   75.90   27.99 26.94 0.00 0.79 298629.9
  Hg (.) 61.30 174.85 31.80 20.79   20.79 4 000 K
  I (.) 106.76 180.67 70.21 20.79 20.07 0.68 0.46 2983000
  I-(.) 195.02   169.15 221.92 20.79 20.79 20 000 K
  I2 (.)   116.14   54.44 40.12 49.79 298385
  I2 (.) 62.43 260.60 19.39 36.90 37.40 0.59 0.71 2983000
  In (.)   57.82   26.74 20.25 21.59 298430
  K (.)   64.18   29.58 5.61 81.17 298335
  La (.)   56.90   27.82 25.8 6.70 2981153
  Li (.)   28.24   24.73 6.86 46.44 3.51 298450
  Mg (.)   32.68   24.89 22.30 10.63 0.42   298920
  M-a   32.01   26.28 23.85 14.14 1.59 298980
  M (.)   28.62   24.06 21.67 6.95 2982890
  N2 (.)   191.50   29.12 27.88 4.27 2982500
  Na (.)   51.21   28.24 16.82 37.82 298371
  Na (.) = 2.60
  Ni-a   29.87   26.07 16.99 29.46     298633
  Ni-b 25.10 7.53 6331725
  O () 249.17 160.95 231.75 21.91 20.80 0.01 0.98 2983000
  O* (.) 1568.78 154.85 1546.96 20.79 20.79 2982500
  O - (.) 101.43 157.69 - 91.20 21.67 20.84 0.02 ' 0.75 2Q83000
  O2 (.)   205.04   29.37 31.46 3.39 3.77 2983000
  O3 (.) 142.26 238.82 162.76 39.25 47.02 8.04 9.04 2981500
  P (.):   41.09   23.82 23.82 273317
  P (.) =0.66 "'"' 26.33 317550
  P (.) 17.45 22.80 12.00 21.39 16.95 14.89 298870
  P2 (.) 143.85 217.94 103.37 32.05 36.16 0.85 4.31 2982000
  Pb (.);   64.81   26.82 24.23 8.71 298601
  / / = f (T) Temepp ep, K  
  a b × 103 ' × 10-5  
  Pb (.) =4.77 32.49 3.09 6011200
  Pt (.)   41.55   25.86 24.02 5.61 2982000
  Ra (.)   (71.2)   (27.2)
  Rb (.)   76.23   30.88 30.88 298310
  S (.) 0.38 32.55 0.19 23.64 23.64 368392
  S (.)   31.92   22.68 22.68 27-8368
  S (.) 278.81 167.75 238.31 23.67
  S2 (.) 128.37 228.03 79.42 32.51 36.11 1.09 3.51 29821900
  Sb (.)   45.69   25.23 23.10 7.28 273900
  Se (.)   42.44   25.36 18.95 23.01 273490
  Si (.)   18.83   19.99 22.B2 3.86 3.54 2981685
  Sn (.)   51.55   26.99 21.59 18.10 298505
  Sn (.) = 7.03 21.54 6.15 12.88 505-800
  Sr (.)   55.69   26.36 22.22 13.89 298830
  Te (.)   49.50   25.71 19.12 22.09 298720
  Th-a   53.39   27.32 23.56 12.72 2981600
  Ti-a   30.63   25.02 21.10 10.54 2981155
  Tl-a   64.18   26.32 22.01 14.48 273500
  U-a   50.29   27.66 16.19 30.63 2.05 298940
  W (.)   32.64   24.27 22.91 4.69 2982500
  Zn (.)   41.63   25.44 22.38 10.04 273690
  Zr-a   38.99   25.44 21.97 11.63 2981135
 
  AgBr (.) 100.42 107.11 97.02 52.30 1 33.18 64.43 298700
  AgCl (.) 126.78 96.23 109.54 50.79 62.26 4.18 11.30 298725
  AgI-a 61.92. 115.48 66.35 . 54.43 24.35 100.83     298420
  AgNO3-a 124.52 140.92 33.60 93.05 36.65 189.12 298433
  Ag2O (.) 30.54 121.75 10.90 65.86 55.48 29.46 298500
  Ag2S-a 31.80. 143.51 39.70 76.53 64.60 39.96 298449
  Ag2SO4 (.) 715.88 200.00 618.36 131.38 96.65 116.73 298597
  lBr3 (.) 513.38 180.25 490.60 100.50 49.95 169.58 298370
  AlCl3 (.) 704.17 109.29 628.58 91.00 77.12 47.83 273453
  AlF3-a 1510.42 66.48 1431.15 75.10 72.26 45.86 9.62 298727
  Al2O3 (p) 1675.69 50.92 1582.27 79.04 114.55 12.89 34.31 2981800
  l2(SO4) 3 (.) 3441.80 239.20 3100.87 259.41 366.31 62.59 112.47 2981100
  AsCl3 (.) 305.01 216.31. 259.16 133.47
  AsCl3 (.) 270.84 328.82 258.04 75.48 82.09 1.00 5.94 2982000
  As2O3 (e) 653.37 122.72 577.03 112;21 59.83 175.73 298582
  As2O3 (pe) 656.89 108.32 576.16 95.65 35.02 203.34 298548
  As2O5 (.) 921.32 105.44 478.69 116.52
  BCl3 (.) 402.96 290.08 387.98 62.63 70.54 11.97 10.21 2981000
  BF3 (.) 1136.58 254.01 1119.93 50.46 52.05 28.03 8.87 2981000
  B2O3 (.) 1270.43 53.84 1191.291 62.76 36.53 106.32 5.48 298723
  BO3 (.) 1210.85 112.13 1132.77 85.35 86.96 48.95 11.97 2981040
  / / = f (T) Temepp ep, K  
  a b × 103 ' × 10-5  
  BaCl2 (.) 859.39 123.64 811.71 75.31 71.13- 13.97     2981195
  Ba(NO3) 2 (.) 992.07 213.80 707.23 151.63 125.73 149.37 16.78 298868
  BO (.) 553.54 70.29 525.84 46.99 53.30 4.35 8.28 2981270
  B(OH)2 (.) 943.49 100.83 855.42 97.91 70.71 91.63   298681
  BaSO4 (.) 1458.88 132.21 1348.43 102.09 141.42 0.0 35.27 2981300
  BeO (.) 598.73 14.14 569.54 25.56 35.35 16.74 13.26 2981175
  BeSO4 (.) . 1200.81 77.97 1089.45 85.69 71.78 99.69 13.78 298863
  Bi2O3 (.) 570.70 151.46 490.23 113.8 103.51 33.47   298978
  O (.) 110.53 197.55 137.15 29.14 28.41 4.10 0.46 2982500
  Co2 (r.) 393.51 213.66 394.37 37.41 44.14. 9.04 8.54 2982500
  OCl2 219.50 283.64- 265.31 57.76. 67.15 12.03 9.04 2981600
  COS (.) 141.70 231.53 168.94 41.55 48.12 8.45 8.20 2981800
  CS2 (.) 88.70 151.04 64.41 75.65  
  CS2 (.) 116.70 237.77 66.55 45.48 52.09 6.69 7.53 2981800
  CaC2-a 59.83 69.96 64.85 62.72 68.62 11.88 8.66 298720
  O3() 1206.83 91.71 1128.35 83.47 104.52 21.92 25.94 2981200
  CaCl2- (.) 795.92 108.37 749.34 72.59 71.88 12.72 2.51 2981055
  F2-a 1220.89 68.45 1168.46 67.03 59.83 30.46 1.97 2981000
  CaHPO4 (.) 1808.56 111.38 1675.38 110.04 138.41 55.10 40.38 2981000
  HPO4×2H2O (.) 2397.46 189.45 2148.60 197.07    
  (H2PO4) 2 (.) 3114.57 189.54 2811.81
  (H2PO4) 2×2H2O (.) 3408.29 259.83 3057.00 258.82
  Ca(NO3) 2 (.) 938.76 193.30 743.49 149.33 122.88 153.97 17.28 298800
  O (.) 635.09 38.07 603.46 42.05 49.62 4.52 6.95 2981800
  (OH) 2 (.) 985.12 83.39 897.52 87.49 105.19 12.01 19.00 298600
  CaS (.) 476.98 56.61 471.93 47.49 42.68 15.90 2981000
  SO4 (p) 1436.28 106.69 1323.90 99.66 70.21 98.74 2981400
  3(PO4)2-a 4120.82 235.98 3884.9 227.82 201.84 166.02 20.92 2981373
  CdCI2 (.) 390.79 115.27 343.24 73.22 61.25 40.17 298841
  CdO (.) 258.99 54.81 229.33 43.64 48.24 6.38 4.90 2981500
  CdS (.) 156.90 71.13 153.16 47.32 53.97 3.77 2981273
  CdS04 (.) 934.41 123.05 823.88 99.62 77.32 77.40 2981273
  lO2 (.) 104.60 257.02 122.34 41.84 48.28 7.53 7.74 2981500
  120 (.) 75.73 266.23 93.40 45.44. 53.18 3.35 7.78 2982000
  CoCl2 (.) 312.54 109.29 269.69 78.49 60.29 61.09 2981000
  CoSO4 (.) 867.76 113.39 760.83 103.22
  13 (.) 556.47 123.01 486.37 91.80 79.50 41.21 2981218
  O3 (.) 590.36 73.22 513.44 69.33 82.55 21.67 17.49 298470
  2O3 (.) 1140.56 81.17 1058.97 104.52 119.37 9.20 15.65 2981800
  CsCl (.) 442.83 101.18 414.61 52.63 49.79 9.54 298918
  CsI (.) 336.81 125.52 331.77 51.88 . 48.53 11.21 . 298894
  CsOH (.) 406.68 77.82 354.71
  CuCl (.) 137.24 87.02 120.06 48.53 38.27 34.38     298703
  CuCI2 (.) 205.85 108.07 161.71 71.88 67.44 17.56 298766
  O (.) 162.00 42.63 134.26 42.30 43.83 16.77 5.88 2981359
  CuS (.) 53.14 66.53 53.58 47.82 44.35 11.05 2981273
  / / = f (T) Temepp ep, K  
  a b × 103 ' × 10-5  
  CuSO4 (.) 770.90 109.20 661.79 98.87 78.53 71.96 298900
  2O (.) 173.18 92.93 150.56 63.64 56.57 29.29 2981500
  CU2S (.) 79.50 120.92 86.27 76.32 39.25 130.54   298376
  D2O (.) 294.60 75.90 243.47 84.31
  D2O.(.) 249.20 198.23 234.55 34.27
  FeCO3 (.) 738.15 95.40 665.09 83.26 48.66 112.13. 298855
  FeO (.) 264.85 60.75 244.30 49.92 50.80 8.61 3.31 2981650
  FeS-a 100.42 60.29 100.78 50.54 0.502 167.36 298411
  FeS-b = 4.39 50.42 11.42 4111468
  FeSO4 (.) 927.59 107.53 819.77 100.58
  FeS2 (.) 177.40 52.93 166.05 62.17 74.81 5.52 12.76 2981000
  .Fe2O3 (.) 822.16 87.45 740.34 103.76 97.74 72.13 12.89 2981000
  Fe304 (.) 1117.13 146.19 1014.17 150.79 86.27 208.92 298866
  Ga2O3 (.) 1089.10 84.98 998.24 92.05 112.88 15.44 21.00 2982068
  GeO2 (e.) 554.71 55.27 500.79 52.09 68.91 9.83 17.70 2981390
  GeO2 (ep.) 580.15 39.71 521.59 50.17 66.61 11.59 17.74 2981300
  HBr (.) 36.38 198.58 53.43 29.14 26.15 5.86 1.09 2981600
  HCN (.) 132.00 201.71 121.58 35.90 39.37 11.30 6.02 2982500
  H1 (.) 92.31 186.79 95.30 29.14 26.53 4.60 1.09 2982000
  HD (.) 0.32 143.70 1.47 29.20 29.25 1.15 2.50 2981500
                            (×106)    
  HF (.) 273.30 173.67 275.41 29.14 26.90 3.43 1.09 2982500
  HI (.) 26.36 206.48 1.58 29.16 26.32 5.94 0.92 2982000
  HNCS (.) 127.61 248.03 112.89 46.40 26.48 76.99 34.18 2981000
                            (×106)    
  HNO3 (.) 173.00 156.16 79.90 109.87
  HNO3 (.) 133.91 266.78 73.78 54.12
  H2O (.) 291.85 (39.33) 4.41 109.50 46.47 100273
                (×106)  
  H2O (.) 285.83 69.95 237.23 75.30 39.02 76.64 11.96 273380 2982500
  H2O (.) 241.81 188.72 228.61 33.61 30.00 10.71 0.33 2982500
  H2O2 (.) 187.86 109.60 120.52 89.33 53.60 117.15 298450
  H2O2 (.) 135.88 234.41 105.74 42.39 52.30 11.88 11.88 2981500
  H2S (.) 20.60 205.70 33.50 33.44 29.37 15.40 2981800
  H2SO4 (.) 813.99 .156.90 690.14 138.91 156.90 28.30 23.46 298553
  HPO4 (.) 1279.05 110.50 1119.20 106.06 49.83 189.24 298316
  H3PO4 (.) 1266.90 200.83 1134.00 106.10
  HgBr2 (.) 169.45 170.31 152.22 75.32 66.58 29.29 298514
  HgCI2 (.) 228.24 140.02 180.90 73.91 69.99 . 20.28 1.89 298550
  HgI2-a 105.44 184.05 103.05 78.24 72.84 16.74 273403
  HgO (.) 90.88 70.29 58.66 44.88 36.04 29.64 298800
  HgS (.) 58.99 82.42 51.42 48.41 43.84 15.27 298800
  Hg2Br2 (.) 207.07 217.70 181.35
  Hg2Cl2 (.) 265.06 192.76 210.81 101.70 92.47 30.96     273-798
  Hg2SO4 (.) 744.65 200.71 627.51 131.96
  / / = f (T) Temepp ep, K  
  a b × 103 ' × 10-5  
In2O3 (.) 925.92 107.95 831.98 92.05  
In2(SO4)3 (.) 2725.50 302.08 2385.87 275.00 200.20 251.04 298943  
KAI(SO4) 2 (.) 2465.00 204.50 2235 193.00 234.10 82.34 58.41 2981000  
KBr (.) 393.80 95.94 380.60 52.30 48.37 13.89 298543  
KC1 (.) 436.68 82.55 408.93 51.49 41.38 21.76 3.22 2981000  
KClO3 (.) 391.20 142.97 289.80 100.25  
K1O4 (.) 430.12 151.04 300.58 112.40  
Kl (.) 327.90 106.40 323.18 53.00 38.84 28.92 4.93 298-955  
KMnO4 (.) 828.89 171.54 729.14 117.57  
KNO3-a 492.46 132.88 392.75 96.29 60.88 118.83 273401  
KOH (.) 424.72 79.28 379.22 65.60 42.66 76.96 298522  
K2O3 (.) 1150.18 155.52 1064.87 114.44 80.29 109.04 6301171  
K2rO4 (.) 1385.74 200.00 1277.84 146.00 123.72 74.89 298939  
K2r2O7 (.) 2067.27 291.21 1887.85 219.70 153.38 229.29 298671  
K2SO4 (.) 1433.69 175.56 1316.04 130.01 120.37 99.58 17.82 298856 t  
LaCl3 (.) 1070.68 144.35 997.07 103.60 97.19 21.46 2981128  
LiCl (.) 408.27 59.30 384.30 48.39 41.42 23.40 298883  
LiNO3 (.) 482.33 71.18 374.92 83.26 38.37 150.62 273523  
LiOH (.) 484.67 42.78 439.00 49.58 50.17 34.48 9.50 298744  
Li2CO3 1216.00 90.16 1132.67 96.20 42.53 177.34 298623  
Li2SO4 1435.86 114.00 1321.28 117.60 118.95 93.34 27.20 298505  
MgCO3 (.) 1095.85 65.10 1012.15 76.11 77.91 57.74 17.41 298750  
MgCI2 (.) 644.80 89.54 595.30 71.25 79.08 5.94 8.62 298900  
MgO (.) 601.49 27.07 569.27 37.20 48.98 3.14 11.44 2983000  
Mg(OH)2 (.) 924.66 63.18 833.75 76.99 46.99 102.85 298541  
MgSO4 (.) 1287.42 91.55 1173.25 95.60 106.44 46.28 21.90 2981400  
MgSO4×6H2O (.) 3089.50 348.10 2635.10 348.10  
MnO3 (.) 881.66 109.54 811.40 81.50 92.01 38.91 19.62 298700  
Mn12 (.) 481.16 118.24 440.41 72.97 75.48 13.22 5.73 298923  
MnO (.) 385.10 61.50 363.34 44.10 46.48 . 8.12 3.68 2981800  
MnO2 (.) 521.49 53.14 466.68 54.02 69.45 10.21 16.23 298523  
MnS (.) 214.35 80.75 219.36 49.92 47.70 7.53   2981800  
Mn2O3 (.) 957.72 110.46 879.91 107.50  
Mn3O4 (.) 1387.60 154.81 1282.91 148.08 144.93 45.27 9.20 2981445  
NH3 (.) 69.87 80.75.  
NH3 (.) 45.94 192.66 16.48 35.16  
NH4Al(SO4)2 (.) 2353.50 216.31 2039.80 226.40 29.80 25.48 1.67 2981800  
NH4Cl-b 314.22 95.81 203.22 84.10  
NH4




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