.


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2. - ,

 

 

: -

 

__________________ ______________

..

(, )

 

____________ ______________

..

(, )

:

- , ;

- - - .

 

- () _________________________

_____________

___________________________________________________

_____________

:

PbO2, KClO3, CrCl3, Ca(HSO4)2, KMnO4, CO2, C2H2, Na2Cr2O7, H2O2.

_________________________________

__________________________________

- ____________________________________________________________

_____________

- _________________________________________________________

_____________

, , ( ):

K Mn O4 - _________; Mn O2 - ___________; Na2 S O3 - _________; K I - _____________;  
P H3 - ____________; Na2 S ___________; V 2O5 - ___________; H N O3 - __________;  

:

1.____________

2.____________

3.___________

- ( , , φ0)

__________________________

, ________________________________

__________________ ;

, ________________________________

__________________ ;

() ____________________

_____________________________, , _________________

 

-

 

1.

 

- ______________________.._________________________,

( ):

1 ______________________________________________________________

2 __________________________________________________________

3 ____________________________________________________________.

, , :

1. :

KMnO4 + Na2SO3 + H2SO4 → MnSO4 + K2SO4 + Na2SO4 + H2O

:

_____________

:

MnO4-_______+________→ Mn2+_________+________ (______________)

SO32-________+________→ SO42-________+________ (______________)

, , :

_____________

.

, :

, φ0 (______________________) =

φ0 (______________________) =

= _________.

2. :

KMnO4 + Na2SO3 + H2O → MnO2 + Na2SO4 + KOH

:

_____________

:

MnO4-_______+________→ MnO2_______+________ (_______________)

SO32-_______+________→ SO42-_______+________ (______________)

, , :

_____________

.

, :

, φ0 (_____________________) =

φ0 (____________________) =

= _________.

3. :

KMnO4 + Na2SO3 + OH → 2MnO4 + K2SO4 + Na2SO4 + H2O

:

________________

:

MnO4-_______+________→ MnO4-_______+________ (______________)

SO32-_______+________→ SO42-_______+_________ (______________)

, , :

________________

.

, :

, φ0 (_____________________) =

φ0 (_____________________) =

= _________.

: ( , - )___________________________________________________

_____________

_____________

_____________

_____________

 

2. - ,

_________________________ , ____________________________________________

:

1____________

2____________

1. :

KMnO4 + NaNO2 + H2SO4 → MnSO4 + K2SO4 + NaNO3 + H2O

:

_____________

:

MnO4-_______+________→ Mn2+ _______+________ (______________)

NO2-_______+________→ NO3- _______+________ (______________)

, , :

_____________

.

2. :

KI + NaNO2 + H2SO4 → I2 + K2SO4 + N2 + H2O

:

_____________

:

I-_______+________ → I2_______+________ (______________)

NO2-_______+________→ NO3-_______+________ (______________)

, , :

_____________

.

: ( ; - , , )______________________________________________________

_____________

_____________

_____________

_____________

 



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