5560. , , , (), .
1 | % | |
1. . N2+3H2=2NH3 +2 = 2.
2. ? ?
3. .
4. ?
5. , ?
6. -.
7. , () , , :
CO2+CaCO3+H2O() Ca(HCO3)2+Q
CaCO3 CO2 + CaO Q
Ca(OH)2 +CO2 CaCO3 + H2O() + Q
CaO+ H2O() Ca(OH)2 + Q
8. (, , ), 3H2+N 2NH3 + 98 /?
9. - ?
1. 600 H2 + J2=2HJ, 0,03 /, 0,04 /. - .
. HJ H2+J2 =2HJ 2 J2, 0,04 HJ 0,02 2 0,02 J2, 0,030,02 = 0,01 .
:
= =
- , ΔG .
ΔG = RT In K = 2,303 RT lg
ΔG= 2,303 8,313 600 Ig 16 = 2,303 8,313 600 1,204 =
= 13830 / = 13,830 /.
, 0,01 /, 16, - 15,798 /.
2. 25 :
22 (.) +22 (.) = 26 (.),
ΔͰ= - 324,2 / ΔS= - 10,22 /.
. - ΔG= RTlnK.
|
|
ΔG= - 2,38,3293lgK (1)
:
ΔG=ΔHTΔS (2)
- (2) , ΔͰ .
ΔG0 = - 324200 298 (- 10,22) = - 327245 /
, (1), lg /:
lgK= -
, ; = 1,139.