CH3─ CH3─CH2─ CH3─CH2─CH2─ CH3─CH─ │ CH3 CH3─CH2─CH2─CH2─ CH3─CH─ CH2─ │ CH3 . CH3─CH2─CH─ │ CH3 CH3 │ . CH3─C─ │ CH3 CH3 │ CH3─C─CH2─ │ CH3 | CH2 ═CH─ CH2 ═CH─CH2─ () CH ≡C─ ─CH2─ CH3 ─ ─ CH3 ─ CH2 ─ ─ CH3─CH2─CH2── |
1
-(2), -(3), -(4), -(5) .. (= ≡) .
.
CnH2n+2 - R―OH -
CnH2n - -
CnH2n-2 - -
CnH2n-2 - -
.
, , ., .
1. , - .
2. , .
3. , .
4. .
2,6--3-
2
CnH2n+2 | CnH2n | CnH2n-2 | CnH2n-2 | CnHn n ≥ 6 | R―OH | |||||
, - | , , | , | 1,2 1,4 , , | , , | , , , | , , , | , , |
|
|
3
,
() | |||
HCOOH | |||
CH3COOH | |||
CH3CH2COOH | |||
CH3(CH2)2COOH | |||
CH3(CH2)3COOH | |||
CH3(CH2)4COOH | |||
CH3(CH2)10COOH | |||
CH3(CH2)12COOH | |||
CH3(CH2)14COOH | |||
CH3(CH2)16COOH | |||
HOOC¾COOH | |||
HOOC-CH2-COOH | |||
HOOC-(CH2)2-COOH | |||
HOOC-(CH2)3-COOH | |||
HOOC-(CH2)4-COOH | |||
CH2=CHCOOH | |||
CH2=C(CH3)COOH | |||
CHºCCOOH | |||
-9- | CH3(CH2)7=(CH2)7COOH | ||
-9,12- | CH3(CH2)3 (2 -=)2(CH2)7COOH | ||
-9,12,15- | CH3 (2 -=)3(CH2)7COOH | ||
-5,8,11,14- | CH3(CH2)4 (2 -=)4(CH2)2COOH | ||
- | HOOC-=-COOH | ||
- | HOOC-=-COOH | ||
C6H5COOH | |||
1,2- | --C6H5 COOH | ||
1,4- | --C6H5 -COOH | ||
1,3- | --C6H5 -COOH |
4
:
α-D- α-D- α-D--1,4- α-D-
:
α-D- α-D- α-D--1,1- α-D-
5
1. | ||
Gly | -H | |
Ala | -CH3 | |
Val | -CH(CH3)2 | |
Leu | -CH2-CH(CH3)2 | |
Ile | -CH(CH3) -CH2-CH3 | |
2. , | ||
Ser | -CH2-OH | |
Thr | -CHOH-CH3 | |
Asp | -CH2-COOH | |
Glu | -CH2-CH2-COOH | |
Asn | -CH2-CO-NH2 | |
Gln | -CH2-CH2-CO-NH2 | |
Lys | -(CH2)4-NH2 | |
Arg | ||
Cys | -CH2-SH | |
Met | -CH2-CH2-S- CH3 | |
3. , | ||
Phe | ||
Tir | ||
4. | ||
Trp | ||
His | ||
Pro |
|
|
6
+ = | + = |
+ = | + = |
+ = | + = |
+ = | + = |
-5'- | 5'- |
-5'- | 5- |
-5'- | 5'- |
-5'- | 5'- |
-5'- | 5'- |
-5'- | 5'- |
-5'- | 5'- |
-5'- | 5'- |