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. 2016 .
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2016 . 1
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1
: ()
50-60% , - 85-90%.
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5. .
6. [5].
, , , - , . - , . , , , , "" , , .
, , :
- 70%;
- 20%;
- 10%.
, , , .
.
, , .
:
1) - , , , 250 . ;
2) . . , 500 3, .
3) ( ) - , .
, 250 , , , , , .
, :
1. (, , );
2. ;
3. -;
4. ;
5. - .
, [5].
Q |
T=500ºC |
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- , - , - ,
Q - , ,
- ;
;
;
- , - .
1 - .
, , Y, ./, [5]:
Y=γ*σ*f*M, (1)
γ , 48, ./.;
σ [5], σ=4;
f , . 1 /, :
f =[100/(100+φ*h)]*[4/(1+υ)], (2)
h , ( );
υ , 3 /;
φ , :
φ=1+∆T/75, (3)
∆T , C, :
∆T=T-t (4)
T - 13 00 [3], 0;
t , C.
M , , ./, [5]:
N
M=∑i*mi (5)
i=1
i i- , ./;
N ;
mi i- , /.
, , ./, :
=Y1Y2, (6)
Y1, Y2 , (1, 2)
, ./, :
. = /Q, (7)
Q , /.
, /, 1 :
1=Q(1*+Nox1*NOx+SO21*SO2+CHx1*CHx+1*) (8)
, ./, 1 :
Y1=γ*σ*f*M1 (9)
, /, 2 :
2=Q(2*+Nox2*NOx+SO22*SO2+CHx1*CHx+2*)(10)
, ./, 2 :
Y2=γ*σ*f*M2 (11)
, ./, :
=Y1Y2 (12)
, ./, :
. = /Q, (13)
4.
( %=4,5%)
Q=50000 /
t=35C
T=500C
σ=4
γ=48 ./.
h=20
υ=3 /
()%
CH3SH = 12+3+32 +1 ==48
1.1. () :
m 4,5 = Q * %= 50000 / * 4,5% / 100% = 2250/
1.2. SO2 :
CH3SH + 3O2 → SO2 +CO2 + 2H2O
:
m 4,5 * 103 * 22,4 / = 2250/ * 103 * 22,4 / 48 = 1050000 3/
1.3. SO2:
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mSO2 4,5= 1050000 3/ * 64 10-3/ 22,4 = 3000 /
1.4. SO2:
SO24,5 = m SO2 / Q = 3000 / * 103 / 50000 / = 60 /
1.5. O:
O= Q * * = 50000 / *23*1*10-3 = 1150,00 ../
NOx:
NOx= Q * NOx * NOx = 50000 / *41*41*10-3 = 84050,00 ../
SO2:
SO2 4,5=Q * SO2 * SO2 = 50000 / * 60 *22,8*10-3 = 68400 ../
CHx:
CHx= Q * CHx * CHx = 50000 / *11*3,16*10-3 = 1738,00 ../
:
= Q * * = 50000 / *8*250*10-3 = 100000,00 ../
4,5:
ΣM4,5=SO2+O+NOx+CHx+= 68400 +1150+84050+1738+100000 =
= 255338../
1.6. [5]:
φ=1+∆T/75=1+465C/75=7,2
∆T=T-t=500C-35C=465C,
, , (3) [5]:
f=[100/(100+7,2 20)]*[4/(1+3)]= 0,41
1.7. :
Y=γ*σ*f*ΣM
4,5%= 484 0,41 255338=20092170,49 ./
1.8. 4,5% () :
=Q*(*+Nx*Nox+SO2*SO2+CHx*CHx+*),
α=95%
mSO2 = (1-95/100) *mSO2=(1-95/100) *3000 /= 150 /,
: SO2 = 150000//50000/=3/
SO2=50000/(3*22,8)10-3=34200,00 ../;
SO2=484*0,41*34200,00 =269114,75 ./
Σ=50000/((10*1+15*41+ 3 *22,8+3*3,16+1*250)10-3=
= 47644,00 ../;
:
4,5%=484* 0,41 *47644,00 =3749036,07 ./
:
=4,5%= 20092170,49 - 3749036,07=16343134,43 ./
:
=16343134,43/50000=326,86 ./
( %=3,5%)
1.1. () :
m 3,5 = Q * %= 50000 / * 3,5% / 100% = 1750,00 /
1.2. SO2 :
CH3SH + 3O2 → SO2 +CO2 + 2H2O
:
m 3,5 * 103 * 22,4 / = 1750,00/ * 103 * 22,4 / 48 = 816666,67 3/
1.3. SO2:
mSO2 3,5= 816666,67 3/ * 64 10-3/ 22,4 = 2333,33 /
1.4. SO2:
SO2 3,5 = mSO2 / Q = 2333,33 / * 103/ 50000 / = 46,67 /
1.5. O:
O= Q * * = 50000 / *23*1*10-3 = 1150,00 ../
NOx:
NOx= Q * NOx * NOx = 50000 / *41*41*10-3 = 84050,00 ../
SO2:
SO2 3,5=Q * SO2 * SO2 = 50000 / * 46,67 *22,8*10-3 = 53200,00 ../
CHx:
CHx= Q * CHx * CHx = 50000 / *11*3,16*10-3 = 1738,00 ../
:
= Q * * = 50000 / *8*250*10-3 = 100000,00 . ./
3,5:
ΣM3,5=SO2+O+NOx+CHx+= 53200,00 +1150+84050+1738+100000 =
= 240138,00../
1.6. [5]:
φ=1+∆T/75=1+465C/75=7,2
∆T=T-t=500C-35C=465C,
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, , (3) [5]:
f=[100/(100+7,2 20)]*[4/(1+3)]= 0,41
1.7. :
Y=γ*σ*f*ΣM
3,5%= 484 0,41 240138,00=18896104,92 ./
1.8. :
=4,5%3,5%= 20092170,49 - 18896104,92 = 1196065,57 ./
1.9. :
.= /Q=1196065,57/50000=23,92 ./
( %=1,0%)
1.1. () :
m 1,0 = Q * %= 50000 / * 1,0% / 100% = 500,00 /
1.2. SO2 :
CH3SH + 3O2 → SO2 +CO2 + 2H2O
:
m 1,0 * 103 * 22,4 / = 500,00 / * 103 * 22,4 / 48 = 233333,333/
1.3. SO2:
mSO2 1,0= 233333,33 3/ * 64 10-3/ 22,4 = 666,67 /
1.4. SO2:
SO2 1,0 = mSO2 / Q = 666,67 / * 103/ 50000 / = 13,33 /
1.5. O:
O= Q * * = 50000 / *23*1*10-3 = 1150,00 ../
NOx:
NOx= Q * NOx * NOx = 50000 /*41*41*10-3 = 84050,00 ../
SO2:
SO2 1,0=Q * SO2 * SO2 = 50000 / * 13,33 *22,8*10-3 = 15200,00 ../
CHx:
CHx= Q * CHx * CHx = 50000 / *11*3,16*10-3 = 1738,00 ../
:
= Q * * = 50000 / *8*250*10-3 = 100000,00 ../
1,0:
ΣM1,0=SO2+O+NOx+CHx+= 15200,00 +1150+84050+1738+100000=
= 202138,00../
1.6. [5]:
φ=1+∆T/75=1+465C/75=7,2
∆T=T-t=500C-35C=465C,
, , (3) [5]:
f=[100/(100+7,2 20) ]*[4/(1+3)]= 0,41
1.7. :
Y=γ*σ*f*ΣM
1,0%= 484 0,41 202138,00= 15905940,98 ./
1.8. :
=4,5%1,0%= 20092170,49 - 15905940,98 = 4186229,51 ./
1.9. :
.= /Q=4186229,51/50000=83,72 ./
( %=0,1%)
1.1. () :
m 0,1 = Q * %= 50000 / * 0,1% / 100% = 50,00/
1.2. SO2 :
CH3SH + 3O2 → SO2 +CO2 + 2H2O
:
m 0,1 * 103 * 22,4 / = 50,00 / * 103 * 22,4 / 48 = 23333,33 3/
1.3. SO2:
mSO2 0,1= 23333,33 3/ * 64 10-3/ 22,4 = 66,67 /
1.4. SO2:
SO2 0,1 = mSO2 / Q = 66,67 / * 103/ 50000 / = 1,33 /
1.5. O:
O= Q * * = 50000 / *23*1*10-3 = 1150,00 . ./
NOx:
NOx= Q * NOx * NOx = 50000 / *41*41*10-3 = 84050,00 ../
SO2:
SO2 0,1=Q * SO2 * SO2 = 50000 / * 1,33 *22,8*10-3 = 1520,00 ../;
CHx:
CHx= Q * CHx * CHx = 50000 / *11*3,16*10-3 = 1738,00 . ./
:
= Q * * = 50000 / *8*250*10-3 = 100000,00 ../
0,1:
ΣM0,1=SO2+O+NOx+CHx+= 1520,00 +1150+84050+1738+100000 =
= 188458,00. ./
1.6. [5]:
φ=1+∆T/75=1+465C/75=7,2
∆T=T-t=500C-35C=465C.
, , (3) [5]:
f=[100/(100+7,2 20)]*[4/(1+3)]= 0,41
1.7. :
Y=γ*σ*f*ΣM
0,1%= 4840,41188458,00=14829481,97 ./
1.8. :
=4,5%0,1%= 20092170,49 - 14829481,97 = 5262688,52 ./
1.9. :
.= /Q=5262688,52/50000=105,25 ./
MK, % . | 0,1 | 3,5 | 4,5 | |
, ./ | 14829481,97 | 15905940,98 | 18896104,92 | 20092170,49 |
4,5 k | 3749036,07 |
2 (. / ) ( ) , % .
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