1. .
, , , .
→ :
V = - = * (2.15)
- = * , :
- ln CA = K * τ + const
const . τ = 0 () (,). , const = - ln C,A
- ln CA = * τ - ln C,
- ln CA + ln C, = * τ
= (2.16)
. , , .
τ, :
= (2.17)
, (τ1/2), , , . , (2.16) :
= = 0,693/ (2.18)
, .
, [K] = -1, -1
2. .
. + → .
:
V = - = * *
τ.
, ,
- = * 2 (2.20)
(-2 * dc = )
const (2.21)
τ = 0, = , const = , - = τ
= ( - ) = () (2.22)
- , :
= () = () (2.23)
≠ :
- = * * = (, - )(, - )
= - * dτ , :
= ln (2.24)