, , , (), (V) ().
:
1. ( ) .
2. ( ), ( ) .
3. , ( , , ) , .
, . , , .
, , .. . .
dG = 0 μi = 0
(, = const) :
+ b + dD
, b, , d , , , D. μ, μ, μ, μD . μi = 0, , , ..
μi = μ + dμD - μ - bμ.
, . , (1.80) μi = μi0 + RT lnpi . μi μi :
μ + dμD - μ - bμ + RT (lnp + dlnpD - lnp - blnp) = 0
ln (μ0 + dμ0D - μ0 - bμ0) (1.83)
, , (1.83) . ln p (1.83)
lnp = ln p
(1.84)
, , .
(1.84) : , , .
. ( ).
|
|
:
= (1.85)
(1.85) .
- i iv = v iRT .
= (1.86)