, , ( ) . , , , ∆rG0, ; .
: 2NO() + O2() = 2NO2(); ∆rG0298 = - 70
22() + O2() = 22O(); ∆rG0298 = - 447 ,
(250). , ∆G > 0, . , (∆G < 0), - - . , , ? , . (∆) (∆G), :
→ (1), , , .
→ ( ) → (2).
, ∆, ∆S, ∆G, .
. , ( , , ) ( ).
, - , .
, ( ).
?
, , . :
V = 
(2.1)
V = 
(2.2)
. (v) (V) () :
|
|
|
,
V = 
= 
(2.3)
, ,
V = 
(2.4)
, , . , . , (2.1) , , (2.3) (2.4) .
, , N2 + 3H2 
2NH3, , . , , , , . :
V = 
(
) (2.5)
( )
V = - 
- 
(2.6)
v aA + v bB + v cC +... → v dD + v eE +...
V = - 
- 
- 
+ 
= + 
(2.7)
tg = f(τ), .
 |
 |
. 2.1 : ,
.
?
, (. * -1). /, ( ), (*-1*-1) (*-1*-1). . : , ( ), , , , ( ), ( ), ( ), ( ), ( ), ( ).
, , () , . , , .
