:
R:N:O: R-N+ O-
O O
.
.
R-N-O- R-N=O
O O
O-1/2
R-N+
O-1/2
N-O , .
H H O
H C C-N+
H H O-
- - NO2.
N O ( =3,5 4,0 ), .
. =1010. . , . 1,132. , , , . .
I. .
CH3NO2 + 6H CH3NH2 + 2H2O
II. .
- . .
1) . -.
H O O O
CH3-C-N CH3-CH=N CH3-CH=N + H2O
H O OH ONa
- -
, . . .
CH3 O CH3 O O
CH3-CH-N CH3-C=N (CH3)2C=N + H2O
O OH ONa
2)
) HNO2 .
O O O O
CH3-CH-N + HO-N=O CH3-CH-N CH3-C-N CH3-C-N
O N=O O N-OH O N-ONa O
, , . .
) HNO2 .
O N=O O
H3-CH-N + HO-N=O H2O + CH3-C - N
CH3 O CH3 O
, ( ).
3)
O O OH O O
CH3-C + CH3-CH2-N CH3-C-CH-N H2O + CH3-CH=C-N
H O H CH3 CH3 O
3--2- 2--2-
.
.
O
HC
H
O H HO-CH2 O2NOCH2
HC + H-C-NO2 HO-CH2-C-NO2 + 3HONO2 O2NOCH2-C-NO2
H H HO-CH2 O2NOCH2
O ()
|
|
HC ()
H
4)
H3-CH2-NO2 + 2Br2 CH3-CBr2-NO2 + 2HBr
1,1- -1-
3. , ..
O
R-N R-O-N=O
O
1.
2.
1.. . .
CH3-O-N=O + 4H CH3OH + NH2OH
2. . (. ). .
CH3-O-N=O + NaOH CH3OH + NaNO2