- , , .
- .
, . .
, . .
, , , , . , , , .
- : , , , .
, , . , , , . , , , , .
, , , , . : ( ) , . , , :
Men++ne- ⇆ Me.
- . , . . , , .
j , , . .
, , , 1 /. 1 . 298 . :
2++2 - ⇆ 2
, ( ), , . , - . ( ) e :
|
|
e = j j,
j (, , );
j (, , ).
, . () ().
, , , - , , .
. j0 , , , ( ) 1 /; =298 ; =1 . ( ).
Men++ne- = Me.
j0, , ( ). , . , 2.10.1, :
2.10.1
φ0, | φ0, | φ0, | |||
Li+/Li | -3,045 | Mn2+/Mn | -1,180 | Pb2+/Pb | -0,126 |
K+/K | -2,925 | Zn2+/Zn | -0,763 | 2H+/H2 | 0,000 |
Ba2+/Ba | -2,906 | Cr3+/Cr | -0,744 | Sb3+/Sb | +0,200 |
Sr2+/Sr | -2,891 | Fe2+/Fe | -0,440 | Bi3+/Bi | +0,230 |
Ca2+/Ca | -2,866 | Cd2+/Cd | -0,403 | Cu2+/Cu | +0,337 |
Na+/Na | -2,714 | Co2+/Co | -0,277 | Hg2+/Hg | +0,854 |
Mg2+/Mg | -2,363 | Ni2+/Ni | -0,250 | Ag+/Ag | +0,799 |
Al3+/Al | -1,662 | Sn2+/Sn | -0,136 | Au3+/Au | +1,498 |
, Men++ne-=Me :
, (2.10.1)
;
R ;
F (96500 /);
n , ;
n+ - .
=298 , :
, (2.10.2)
, /.
, ( ) ( ) ; ; (), (); , , , . -, , :
|
|
Zn / ZnSO4 // CuSO4 /Cu Zn / Zn2+// Cu2+/ Cu.
1
: 2S, Na2S2O3, H2SO3, H2SO4.
:
- ;
- ;
- , ;
- ;
- +1, , -1;
- , , -2;
- -1;
- +1;
- +2
.
(+12S)0
2(+1) + = 0
= -2.
(Na+12S2O-23)0
2(+1) + 2 + 3(-2) =0,
= +2.
(H+12SO-23)0
2(+1) + + 3(-2) =0
= +4.
(H+12SO-24)0
2(+1) + + 4(-2) =0,
= +6.
2
-
FeSO4 + KMnO4 + H2SO4 "Fe2(SO4)3 + MnSO4+ K2SO4 + H2O
, , , (II) (), (VII) (II).
Fe+2 1- " Fe+3, Mn+7 + 5- " Mn+2
. , .
2Fe+2 2- " 2Fe+3 ´ 5
Mn+7 + 5- " Mn+2 ´ 2
10Fe+2 + 2Mn+7 " 10Fe+3 + 2Mn+7
, :
10FeSO4 + 2KMnO4 + H2SO4 " 5Fe2 (SO4)3 + 2MnSO4+ K2SO4 + H2O
- :
(3´5 + 2 + 1) 10 = 8
10FeSO4 + 2KMnO4 + 8H2SO4 " 5Fe2 (SO4)3 + 2MnSO4+ K2SO4 + H2O
, 8, , .
, - :
10FeSO4 + 2KMnO4 + 8H2SO4 " 5Fe2 (SO4)3 + 2MnSO4+ K2SO4 + 8H2O
, - .
- , , . , , , , .
- - .
- , , , .
|
|
- , .
- . , : 2, +, .
, , -.
, - .
- : . . .
- , . .
- .
, - - .
- . , - , .
2Fe2+ 2- " 2Fe3+ ´5
(MnO4) + 8+ + 5- " Mn2+ + 4 H2O ´2
10Fe2+ + 2(MnO4) + 16+ " 10Fe3+ + 5 Mn2+ + 8H2O
10FeSO4 + 2KMnO4 + 8H2SO4 " 5Fe2(SO4)3 + 2MnSO4+ K2SO4 + 8H2O
3
.
Na2SO3 + KMnO4 + KOH " Na2SO4 +
Na2AsO3 ,
S+4 -2- " S+6,
KMnO4 .
, Mn+7
-, :
>7 (MnO4)2
Mn+7 =7 MnO2
< 7 Mn2+
, >7, 2MnO4 .
Na2SO3 + KMnO4 + KOH " Na2SO4 + 2MnO4 + H2O
:
Mn+7 + 1- " Mn+6 ´2
S+4 - 2-" S+6 ´1
Na2SO3 + 2KMnO4 + 2KOH " Na2SO4 + 22MnO4 + H2O
4
-0,14
-0,13 . 25 0, Sn2+ 0,1 /, Pb2+ 0,001 /?
, Pb2+ + 2e - =Pb Sn2+ + 2e - =Sn , . :
.
jSn = -0,14 + 0,059: 2 ×lg0,1 = -0,17 ;
jPb = -0,13 + 0,059: 2 ×lg0,001 = -0,22 .
, , .
5
, (II) :
101 / 104 /. , 100%, 298 . . , ? , , .
|
|
, , :
.
0,126 ; n =2, Pb2++ 2- =Pb .
, 10 1 /. , ,
.
, 10 4 /:
.
, . , , 0,1 , , , 0,0001 .
:
(-) Pb / Pb2+ (0,0001 )// Pb2+ (0,1 )/ Pb (+).
( ), ( ).
:
=j1 j2 = -0,156 (-0,244)=0,088 ().
(): Pb 2e- = Pb2+.
(): Pb2+ + 2e- = Pb.
3.1. :
- (1 30)
- (31 57)
- (58 87)
- . (88 108)
- , , (109 140)
- (141 160)
- (161 178)
- (179 191)
- - (192 216)
- - (217 249)
3.1
1; 31; 58; 88; 109; 141; 161; 179; 215; 235 | |
2; 32; 59; 89; 140; 142; 162; 180; 214; 249 | |
3; 33; 60; 90; 139; 143; 163; 181; 213; 248 | |
4; 34; 61; 91; 138; 144; 164; 182; 212; 247 | |
5; 35; 62; 92; 137; 145; 165; 183; 211; 246 | |
6; 36; 63; 93; 136; 146; 166; 184; 210; 245 | |
7; 37; 64; 94; 135; 147; 167; 185; 209; 244 | |
8; 38; 65; 95; 134; 148; 168; 186; 208; 243 | |
9; 39; 66; 96; 133; 149; 169; 187; 207; 242 | |
10; 40; 67; 97; 132; 150; 170; 188; 206; 241 | |
11; 41; 68; 98; 131; 151; 171; 189; 205; 240 | |
12; 42; 69; 99; 130; 152; 172; 190; 204; 249 | |
13; 43; 70; 100; 129; 153; 173; 191; 203; 248 | |
14; 44; 71; 101; 128; 154; 174; 179; 202; 237 | |
15; 45; 72; 102; 127; 155; 175; 180; 201; 236 | |
16; 46; 73; 103; 126; 156; 176; 181; 200; 235 | |
17; 47; 74; 104; 125; 157; 177; 182; 199; 234 | |
18; 48; 75; 105; 124; 158; 178; 183; 198; 233 | |
19; 49; 76; 106; 123; 159; 161; 184; 197; 232 | |
20; 50; 77; 107; 122; 160; 162; 185; 196; 231 | |
21; 51; 78; 108; 121; 141; 163; 186; 195; 230 | |
22; 52; 79; 89; 120; 142; 164; 187; 194; 229 | |
23; 53; 80; 90; 119; 143; 165; 188; 193; 228 | |
24; 54; 81; 91; 118; 144; 166; 189; 192; 227 | |
25; 55; 82; 92; 117; 145; 167; 190; 216; 226 | |
26; 56; 83; 93; 116; 146; 168; 191; 215; 225 | |
27; 57; 84; 94; 115; 147; 169; 179; 214; 224 | |
28; 31; 85; 95; 114; 148; 170; 180; 213; 223 | |
29; 32; 86; 96; 113; 149; 171; 181; 212; 222 | |
30; 33; 87; 97; 112; 150; 172; 182; 211; 221 | |
1; 34; 58; 98; 111; 151; 173; 183; 210; 220 | |
2; 35; 59; 88; 110; 152; 174; 184; 209; 219 | |
3; 36; 60; 100; 109; 153; 175; 185; 208; 218 | |
4; 37; 61; 101; 118; 154; 176; 186; 207; 217 | |
6; 38; 62; 102; 140; 155; 177; 187; 206; 249 | |
7; 39; 63; 103; 139; 156; 178; 188; 205; 248 | |
8; 40; 64; 104; 138; 157; 161; 189; 204; 247 | |
9; 41; 65; 105; 137; 158; 162; 190; 203; 246 | |
10; 42; 66; 106; 136; 159; 163; 191; 202; 245 | |
11; 43; 67; 107; 135; 160; 164; 179; 201; 244 | |
12; 44; 68; 108; 134; 141; 165; 180; 200; 243 | |
13; 45; 69; 89; 133; 142; 166; 181; 199; 242 | |
14; 46; 70; 90; 132; 143; 167; 182; 198; 241 | |
15; 47; 71; 91; 131; 144; 168; 183; 197; 240 | |
16; 48; 72; 92; 130; 145; 169; 184; 196; 239 | |
17; 49; 73; 93; 129; 146; 170; 185; 195; 238 | |
18; 50; 74; 94; 128; 147; 171; 186; 194; 237 | |
19; 52; 75; 95; 127; 148; 172; 187; 193; 236 | |
20; 53; 76; 96; 126; 149; 173; 188; 192; 235 | |
21; 54; 77; 97; 125; 150; 174; 189; 216; 234 | |
22; 55; 78; 98; 124; 151; 175; 190; 215; 233 | |
23; 56; 79; 99; 123; 152; 176; 191; 214; 232 | |
24; 57; 80; 88; 122; 153; 177; 179; 213; 231 | |
25; 31; 81; 101; 121; 154; 178; 180; 212; 230 | |
26; 32; 82; 102; 120; 155; 161; 181; 211; 229 | |
27; 33; 83; 103; 119; 156; 162; 182; 210; 228 | |
28; 34; 84; 104; 118; 157; 163; 183; 209; 227 | |
29; 35; 85; 105; 117; 158; 164; 184; 208; 226 | |
30; 36; 86; 106; 116; 159; 165; 185; 207; 225 | |
1; 37; 87; 107; 115; 160; 166; 186; 206; 224 | |
2; 38; 58; 108; 114; 141; 167; 187; 205; 223 | |
3; 39; 59; 89; 113; 142; 168; 188; 204; 222 | |
4; 40; 60; 90; 112; 143; 169; 189; 203; 221 | |
5; 41; 61; 91; 111; 144; 170; 190; 202; 220 | |
6; 42; 62; 92; 110; 145; 171; 191; 201; 219 | |
7; 43; 63; 99; 109; 146; 172; 179; 200; 218 | |
8; 44; 64; 94; 128; 147; 173; 180; 199; 217 | |
9; 45; 65; 95; 140; 148; 174; 181; 198; 249 | |
10; 46; 66; 96; 139; 149; 175; 182; 197; 248 | |
11; 47; 67; 97; 138; 150; 176; 183; 196; 247 | |
12; 48; 68; 98; 137; 151; 177; 184; 195; 246 | |
13; 49; 69; 99; 136; 152; 178; 185; 194; 245 | |
14; 50; 70; 100; 135; 153; 161; 186; 193; 244 | |
15; 51; 71; 88; 134; 154; 162; 187; 192; 243 | |
16; 52; 72; 89; 133; 155; 163; 188; 216; 242 | |
17; 53; 73; 90; 132; 156; 164; 189; 215; 241 | |
18; 54; 74; 91; 131; 157; 165; 190; 214; 240 | |
19; 55; 75; 92; 130; 158; 166; 191; 213; 239 | |
20; 56; 76; 93; 129; 159; 167; 179; 212; 238 | |
21; 57; 77; 94; 128; 160; 168; 180; 211; 237 | |
22; 51; 78; 95; 127; 141; 169; 181; 210; 236 | |
23; 31; 79; 96; 126; 142; 170; 182; 209; 235 | |
24; 32; 80; 97; 125; 143; 171; 183; 208; 234 | |
25; 33; 81; 98; 124; 144; 172; 184; 207; 233 | |
26; 34; 82; 99; 123; 145; 173; 185; 206; 232 | |
27; 35; 83; 100; 122; 146; 174; 186; 205; 231 | |
28; 36; 84; 101; 121; 147; 175; 187; 204; 230 | |
29; 37; 85; 102; 120; 148; 176; 188; 203; 229 | |
30; 38; 86; 103; 119; 149; 177; 189; 202; 228 | |
1; 39; 87; 104; 118; 150; 178; 190; 201; 227 | |
2; 40; 58; 105; 117; 151; 161; 191; 200; 226 | |
3; 41; 59; 106; 116; 152; 162; 179; 199; 225 | |
4; 42; 60; 107; 115; 153; 163; 180; 198; 224 | |
5; 43; 61; 108; 114; 154; 164; 181; 197; 223 | |
6; 44; 62; 102; 113; 155; 165; 182; 196; 222 | |
7; 45; 63; 103; 112; 156; 166; 183; 195; 221 | |
8; 46; 64; 104; 111; 157; 167; 184; 194; 220 | |
9; 47; 65; 105; 110; 158; 168; 185; 193; 219 | |
10; 48; 66; 106; 109; 159; 169; 186; 192; 218 | |
11; 49; 67; 107; 138; 160; 170; 187; 201; 217 |
|
|
1 2
3.2. :
- (1 30)
- (31 57)
- (58 78)
- (79 87)
- (88 98)
- (99 108)
- , (109 130)
- (131 140)
- (141 160)
- (161 178)
- (179 191)
- - (192 216)
- - (217 241)
- (242 249)
3.2
1 | 2 | |
1; 31; 58; 79; 88; 108; 109 | 131; 160; 161; 187; 192; 226; 232; 246 | |
2; 32; 59; 87; 89; 107; 110 | 132; 159; 162; 186; 193; 225; 233; 245 | |
3; 33; 60; 86; 90; 106; 111 | 133; 158; 163; 185; 194; 224; 234; 244 | |
4; 34; 61; 85; 91; 105; 112 | 134; 157; 164; 184; 195; 223; 235; 243 | |
5; 35; 62; 84; 92; 104; 113 | 135; 156; 165; 183; 196; 222; 236; 242 | |
6; 36; 63; 83; 93; 103; 114 | 136; 155; 166; 182; 197; 221; 237; 249 | |
7; 37; 64; 82; 94; 102; 115 | 137; 154; 167; 181; 198; 220; 238; 248 | |
8; 38; 65; 81; 95; 101; 116 | 138; 153; 168; 180; 199; 219; 239; 247 | |
9; 39; 67; 80; 96; 100; 117 | 139; 152; 169; 179; 200; 218; 240; 246 | |
10; 40; 68; 79; 97; 99; 118 | 140; 151; 170; 191; 201; 217; 241; 245 | |
11; 41; 69; 87; 98; 108; 119 | 131; 150; 171; 190; 202; 231; 232; 244 | |
12; 42; 70; 86; 88; 107; 120 | 132; 149; 172; 189; 203; 230; 233; 243 | |
13; 43; 71; 85; 89; 106; 121 | 133; 148; 173; 188; 204; 229; 234; 242 | |
14; 44; 72; 84; 90; 105; 122 | 134; 147; 174; 187; 205; 228; 235; 249 | |
15; 45; 73; 83; 91; 104; 123 | 135; 146; 175; 186; 206; 227; 236; 248 | |
16; 46; 74; 82; 92; 103; 124 | 136; 145; 176; 185; 207; 226; 237; 247 | |
17; 47; 75; 81; 93; 102; 125 | 137; 144; 177; 184; 208; 225; 238; 246 | |
18; 48; 76; 80; 94; 101; 126 | 138; 143; 178; 183; 209; 224; 239; 245 | |
19; 49; 77; 79; 95; 100; 127 | 139; 142; 161; 182; 210; 223; 240; 244 | |
20; 50; 78; 87; 96; 99; 128 | 140; 141; 162; 181; 211; 222; 241; 243 | |
21; 51; 58; 86; 97; 108; 129 | 131; 160; 163; 180; 212; 221; 232; 242 | |
22; 52; 59; 85; 98; 107; 130 | 132; 159; 164; 179; 213; 220; 233; 249 | |
23; 53; 60; 84; 88; 106; 109 | 133; 158; 165; 191; 214; 219; 234; 248 | |
24; 54; 61; 83; 89; 105; 110 | 134; 157; 166; 190; 215; 218; 235; 247 | |
25; 55; 62; 82; 90; 104; 111 | 135; 156; 167; 189; 216; 217; 236; 246 | |
26; 56; 63; 81; 91; 103; 112 | 136; 155; 168; 188; 192; 231; 237; 245 | |
27; 57; 64; 80; 92; 102; 113 | 137; 154; 169; 187; 193; 230; 238; 244 | |
28; 31; 65; 79; 93; 101; 114 | 138; 153; 170; 186; 194; 229; 239; 243 | |
29; 32; 66; 87; 94; 100; 115 | 139; 152; 171; 185; 195; 228; 240; 242 | |
30; 33; 67; 86; 95; 99; 116 | 140; 151; 172; 184; 196; 227; 241; 249 | |
1; 34; 68; 85; 96; 108; 117 | 131; 150; 173; 183; 197; 226; 232; 248 | |
2; 35; 69; 84; 97; 107; 118 | 132; 149; 174; 182; 198; 225; 233; 247 | |
3; 36; 70; 83; 98; 106; 119 | 133; 148; 175; 181; 199; 224; 234; 246 | |
4; 37; 71; 82; 88; 105; 120 | 134; 147; 176; 180; 200; 223; 235; 245 | |
6; 38; 72; 81; 89; 104; 121 | 135; 146; 177; 179; 201; 222; 236; 244 | |
7; 39; 73; 80; 90; 103; 122 | 136; 145; 178; 191; 202; 221; 237; 243 | |
8; 40; 74; 79; 91; 102; 123 | 137; 144; 161; 190; 203; 220; 238; 242 | |
9; 41; 75; 87; 92; 101; 124 | 138; 143; 162; 189; 204; 219; 239; 248 | |
10; 42; 76; 86; 93; 100; 125 | 139; 142; 163; 188; 205; 218; 240; 247 | |
11; 43; 77; 85; 94; 99; 126 | 140; 141; 164; 187; 206; 217; 241; 246 | |
12; 44; 78; 84; 95; 108; 127 | 131; 160; 165; 186; 207; 231; 232; 245 | |
13; 45; 58; 83; 96; 107; 128 | 132; 159; 166; 185; 208; 230; 233; 244 | |
14; 46; 59; 82; 97; 106; 129 | 133; 158; 167; 184; 209; 229; 234; 243 | |
15; 47; 60; 81; 98; 105; 130 | 134; 157; 168; 183; 210; 228; 235; 242 | |
16; 48; 61; 80; 88; 104; 109 | 135; 156; 169; 182; 211; 227; 236; 249 | |
17; 49; 62; 79; 89; 103; 110 | 136; 155; 170; 181; 212; 226; 237; 248 | |
18; 50; 63; 87; 90; 102; 111 | 137; 154; 171; 180; 213; 225; 238; 247 | |
19; 52; 64; 86; 91; 101; 112 | 138; 153; 172; 179; 214; 224; 239; 246 | |
20; 53; 65; 85; 92; 100; 113 | 139; 152; 173; 191; 215; 223; 241; 245 | |
21; 54; 66; 84; 93; 99; 114 | 140; 151; 174; 190; 216; 222; 240; 244 | |
22; 55; 67; 83; 94; 108; 115 | 131; 150; 175; 189; 192; 221; 232; 243 | |
23; 56; 68; 82; 95; 107; 116 | 132; 149; 176; 188; 193; 220; 233; 242 | |
24; 57; 69; 81; 96; 106; 117 | 133; 148; 177; 187; 194; 219; 234; 249 | |
25; 31; 70; 80; 97; 105; 118 | 134; 147; 178; 186; 195; 218; 235; 248 | |
26; 32; 71; 79; 98; 104; 119 | 135; 146; 161; 185; 196; 217; 236; 247 | |
27; 33; 72; 87; 88; 103; 120 | 136; 145; 162; 184; 197; 231; 237; 246 | |
28; 34; 73; 86; 89; 102; 121 | 137; 144; 163; 183; 198; 230; 238; 245 | |
29; 35; 74; 85; 90; 101; 122 | 138; 143; 164; 182; 199; 229; 239; 244 | |
30; 36; 75; 84; 91; 100; 123 | 139; 142; 165; 181; 200; 228; 240; 243 | |
1; 37; 76; 83; 92; 99; 124 | 140; 141; 166; 180; 201; 227; 241; 242 | |
2; 38; 77; 82; 93; 108; 125 | 131; 160; 167; 179; 202; 226; 232; 249 | |
3; 39; 78; 81; 94; 107; 126 | 132; 159; 168; 191; 203; 225; 233; 248 | |
4; 40; 58; 80; 95; 16; 127 | 133; 158; 169; 190; 204; 224; 234; 247 | |
5; 41; 59; 79; 96; 105; 128 | 134; 157; 170; 189; 205; 223; 235; 246 | |
6; 42; 60; 87; 97; 104; 129 | 135; 156; 171; 188; 206; 222; 236; 245 | |
7; 43; 61; 86; 98; 103; 130 | 136; 155; 172; 187; 207; 221; 237; 244 | |
8; 44; 62; 85; 88; 102; 109 | 137; 154; 173; 186; 208; 220; 238; 243 | |
9; 45; 63; 84; 89; 101; 110 | 138; 153; 174; 185; 209; 219; 239; 242 | |
10; 46; 64; 83; 90; 100; 111 | 139; 152; 175; 184; 210; 218; 240; 249 | |
11; 47; 65; 82; 91; 99; 112 | 140; 151; 176; 183; 211; 217; 241; 248 | |
12; 48; 66; 81; 92; 108; 113 | 131; 150; 177; 182; 212; 231; 232; 247 | |
13; 49; 67; 80; 93; 107; 114 | 132; 149; 178; 181; 213; 230; 233; 246 | |
14; 50; 68; 79; 94; 106; 115 | 133; 148; 161; 180; 214; 229; 234; 245 | |
15; 51; 69; 87; 95; 105; 116 | 134; 147; 162; 179; 215; 228; 235; 244 | |
16; 52; 70; 86; 96; 104; 117 | 135; 146; 163; 191; 216; 227; 236; 243 | |
17; 53; 71; 85; 97; 103; 118 | 136; 145; 164; 190; 192; 226; 237; 242 | |
18; 54; 72; 84; 98; 102; 119 | 137; 144; 165; 189; 193; 225; 238; 249 | |
19; 55; 73; 83; 88; 101; 120 | 138; 143; 166; 188; 194; 224; 239; 248 | |
20; 56; 74; 82; 89; 100; 121 | 139; 142; 167; 187; 195; 223; 240; 247 | |
21; 57; 75; 81; 90; 99; 122 | 140; 141; 168; 186; 196; 222; 241; 246 | |
22; 51; 76; 80; 91; 108; 123 | 131; 160; 169; 185; 197; 221; 232; 245 | |
23; 31; 77; 79; 92; 107; 124 | 132; 159; 170; 184; 198; 220; 233; 244 | |
24; 32; 78; 87; 93; 106; 125 | 133; 158; 171; 183; 199; 219; 234; 243 | |
25; 33; 58; 86; 94; 105; 126 | 134; 157; 172; 182; 200; 218; 235; 242 | |
26; 34; 59; 85; 95; 104; 127 | 135; 156; 173; 181; 201; 217; 236; 249 | |
27; 35; 60; 84; 96; 103; 128 | 136; 155; 174; 180; 202; 231; 237; 248 | |
28; 36; 61; 83; 97; 102; 130 | 137; 154; 175; 179; 203; 230; 238; 247 | |
29; 37; 62; 82; 98; 101; 129 | 138; 153; 176; 191; 204; 229; 239; 246 | |
30; 38; 63; 81; 88; 100; 109 | 139; 152; 177; 190; 205; 228; 240; 245 | |
1; 39; 64; 80; 89; 99; 110 | 140; 151; 178; 189; 206; 227; 241; 244 | |
2; 40; 65; 79; 90; 108; 111 | 131; 150; 161; 188; 207; 226; 232; 243 | |
3; 41; 66; 87; 91; 107; 112 | 132; 149; 162; 187; 208; 225; 233; 242 | |
4; 42; 67; 86; 92; 106; 113 | 133; 148; 163; 186; 209; 224; 234; 249 | |
5; 43; 68; 85; 93; 105; 114 | 134; 147; 164; 185; 210; 223; 235; 248 | |
6; 44; 69; 84; 94; 104; 115 | 135; 146; 165; 184; 211; 222; 236; 247 | |
7; 45; 70; 83; 95; 103; 116 | 136; 145; 166; 183; 212; 221; 237; 246 | |
8; 46; 71; 82; 96; 102; 117 | 137; 144; 167; 182; 213; 220; 238; 245 | |
9; 47; 72; 81; 97; 101; 118 | 138; 143; 168; 181; 214; 219; 239; 244 | |
10; 48; 73; 80; 98; 100; 119 | 139; 142; 169; 180; 215; 218; 240; 243 | |
11; 49; 74; 79; 88; 99; 120 | 140; 141; 170; 179; 216; 217; 241; 242 |