Q = f (), ln = f (T) 'max = φ (), , , . (Q0 μ c) . .
, . ( ) . .
QpA'maxp = AG0
Q = f () A'maxp = ΔG = φ(T) (56) (223),
Qp = Q0 + αT + βT2 + γT3
-A'maxp = ΔG = Q0 - αT ln - βT2 - γ3/2 - RTC,
, = 0 Qp m = ΔG , . . (. 45). Qp = f (T) , Qp Q0.
A'max ΔG = φ(T) , - , .
l ,
(1906 .) , , Qp
, . . Qp = f () ΔG = φ (T) = 0, , . , , , :
, , . Qp = f (T) ΔG = φ () :
(122) [ (ΔG) T]p → 0:
(246)
T = 0
ΔG=ΔG0=ΔH0.
, .
(246) - ,
|
|
,
(247)
, ΔG =φ (T), , K, .
lg = f () ΔG = φ (T) , . , .
Qp = f{T) (56) , Q0 const,
T = 0 α = δQp/dT. {δQ/dT)T=o = 0, α=0, ,
δQp/dT = 2βT + γ2 +.
ΔG == αT ln T βT2 ,5γ3 RTC QP0 = const
α=0,
=0
=0 CR=0. R , = 0. , ΔG = φ (T) In Kp = f (T) . ,
(248)
(248) , .
, , V = const ΔF = -RT ln Kc = QVo βT2; = const ΔG = RT ln Kp = QPo βT2. - A'maxp A'maxv
(249)
(249) dT 2.
, ;
.
:
= 0 ( ) . ,
, = 0, ,
,
. (250)
, , (250).
, . , , (54) ,
δQ/dT = μ2 μ1 = Δμ.
(δQ/dT)T→0 = 0. , , , . .
(251)
. , , : , 0 , .
, .
(119) (120) :
|
|
, ,
;
T=0
.
,
. (252)
, , .
(1912 .). , = 0 , , . .
. (253)
. (253), S .
, , , = const.
dS = δQ/T.
δQ = μdT,
.
, :
.
S0 = 0,
. (254)
, μ = f(T), .