, ,
, | (3.49) |
.
S ( ) ; . 1865 .. ΔQ T:
dS =
S = k ln Z,
Z , , , ( ), k = 1,3806504*10-23/ . Z, , .. - , .
. .
.
(9.28) |
(9.28) .
(9.27) (9.28),
(9.29) |
, ( ) ( ).
, .
S , ,
1. A B ,
.
2.
,
T .
. .
, . , ,
dS. = .
S2 S1 = dS. > Þ . > . (5.6)
, - .