Zn, Cu, Al CuSO4,, ZnSO4, Al2(SO4)3, FeCl3.
(..2) :
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- :
:
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, . 1.
1
CuSO4 | ZnSO4 | Al2(SO4)3 | FeCl3 ( K3[Fe(CN)6]) | |
Zn | ||||
Cu | ||||
Al |
1. ? . _______________________
2. . () - .
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3. .
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2.
- . .
=
. . .
1. , - .
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2. (. .2), . () , (∆G0) () .
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3. , :
|
|
) 0,001 ZnSO4 1 uSO4; )1 ZnSO4 0,001 M uSO4.
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.
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4. , Zn- Cu- () (H2SO4)? ? .
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5. , ? ? ?
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6. , .
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, CuSO4, KI, NaCl. : (U‑ , ), , ‑24 ‑2 0,5 CuSO4, KI, NaCl.
3.1.
1. . , ?
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2. ? ? SO42 ?
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1. CuSO4 :
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2. ?
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3.2.
1. . ? ? ? ?
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2. , ? ? .
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|
|
1. C NaCl :
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2. ?
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3.3.
1. . ? ? ? ?
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2. ? ?
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1. KI :
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2. ?
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3. . , .
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1. Pt, H2 |2H+ || Cu2+ | Cu Cu | Cu 2+ || Ag+ | Ag , . . 0 , G0298 .
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2. CAg+ = 101 / Ag+ = 104 / . . ∆G. ? , .
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3. 1 gCl2 . - . , , 22,4 (..). , BT = 80 %?
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4. (Fe) . , 1 .
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