- , , N4+. , , . + N+ , .
+
: NaHC4H4O6 ( ) Na3 [Co(N2)6 ], ( () ).
1 .ij NaHC4H4O6:
Cl + NaHC4H4O6 = HC4H4O6 + NaCl
HC4H4O6.
2. ij ()
䳿 .
2 Ѳ + Na3 [ Co(N2)6 ] = 2 Na[ Co(N2)6 ] + 2 NaѲ
, , .
Na+
Na+ (V) [Sb (OH)6], (V) :
NaѲ + [Sb(OH) 6] → Na [Sb(OH)6]↓+ Ѳ
N4+
1. ij N,
N3.
N4Ѳ + N = NѲ + 2 + N3↑
2.
2-3 , . г :
N4Ѳ + 2 2 (gI4) + 4 =
g
= ( N2) + Ѳ + 7 ʲ + 32
g
- 2+, 2+, g2+. - , . (N4)23, 3 3, g2+ , (g)23.
: .
2+
1. 2r4. :
2l2 + 2r4 →4 ↓+ 2l
2. 2S4 . 2+ :
l2 + 2S4 → S4↓ + 2Ѳ
2+:
1. (N4)224. 䳿 2+ 24:
2+ + 242- = 24↓
24 , .
g2+
1. . N g()2:
|
|
|
gѲ2 + 2N = g()2↓+ 2NѲ
2. . ó N24 N4 g2+ --:
gѲ2 + N4 + N4Ѳ + N24 = gN44 ↓ + 2NѲ + 2 + N4Ѳ
