.
1) ?
2) ?
3) ?
4) ?
5) ?
6) . ?
7) ?
8) . (.7).
9) :
. | - | . |
: |
: - ( ).
I
.
.
. I.1, , , .
, .1.1, . - (.1, .2) , ( ).
(. 1), . . (. . 1.2).
, . (. . 1.3). .
.1.1
. . | |||
1.1. | (11) | -: , r, nD20 | - ( ). - (r> < 1) |
-1 (12) | |||
-1 (13) | |||
(14) | |||
1- (15) | |||
1.2. | (6H14) c-1 (6H12) -1 (6H10) (7H8) 1- (4H9 Br) | 1. - - : ; n 2. . 3. C c : , | - (, ) () |
1.3. | 1- | ( ): ? | - |
1.4.1. | -1 -1 | CH3(CH2)3CH=CH2 + +Br2/H2O CH3(CH2)3CºCH + + Br2/H2O | |
1.4.2. | -1 -1 | CH3(CH2)3CH=CH2 + KMnO4/ Na2CO3 CH3(CH2)3CºCH + KMnO4/ Na2CO3 | KMnO4 |
1.4.3. | -1 | CH3(CH2)3CºCH + + Cu(NH3)2OH CH3(CH2)3CºCH + + Ag(NH3)2OH | - |
1.5. | |||
1.6. | KMnO4 | ||
1.7. | 1- | CH3CH2CH2CH2-Br + + AgONO2, |
|
|