TlIn(Ga)S(Se)2 .[7] TlInS2 . ³ , , . , , TlInS2, TlGaSe2 [8].
TlInS2 TlGaSe2 - , GaSe4 InS4, 璺 (. 1.7) [11]. TlInSe2 GaSe 2.39 Å, SeGaSe 109.5 [11]. Tl . , 90, 璺 Tl1+. Tl Se, TlSe6 . TlSe 3.45 Å, Tl-Tl 3.81 Å. TlInS2 TlGaSe2 , . 2.1.
.1.7. TlInS2 TlInSe2 [7]. b. |
1.1. TlInS2 TlInSe2 .
. | a (Å) | b (Å) | c (Å) | b () | Z | |
TlInS2 [11, 12] | 10.90 | 10.94 | 15.18 | 100.21 | ||
TlInSe2 [10, 11] | 10.772 | 10.771 | 16.636 | 100.6 |
ε ε(T) TlInS2 190-220 K [7, 8]. Ti ~ 216 K , Tc ~ 190-195 K . TlInSe2 Ti ~ 120 K Tc ~ 110 K , (Ps) [9].
TlInS2 TlGaSe2 , - ; q c = (0, 0, 0.25). , q = (d, d, 0.25), d , d = 0.012 TlInS2 d = 0.02 TlGaSe2 [10].
, -TIInS2 , c: c = c, 2c, 4c, 8 (c 15 Å, c ) = 10.90 Å, b = 10.94 Å a = 90 c b = 100.21 Å [6]. -TIInS2 c = 15 Å, , ' --. . ³ b . .[5]
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, , ε () (T = 190220 ) TlInS2 . , , ε () , , . , -TIInS2 , [5,12]. 볿 TIInS2 [7]. , TlInS2 216, 206, 204, 201 190-195 K. [8-11].
(, ) - TlInS2 Tc1 = 204 K Tc2 = 201 K. Ti2 = 206 K , e(T) 190-195 K , Tc1 = 204 K Tc2 = 201 K, Tc1 = 204 K Tc2 = 201 K - [14]. Ti = 216 K Ti2 = 206 K I II . , e (T) e (T) e (T) e (T).
, T =204 . : Ti = 216 , 204216 (1), T = 204 - (2), 201204 , Tc = 201 . , . [16]
TlGaSe2 , = 1072 . , = 120 = 107¸120 [14]. , TlGaSe2 = 107 = 120 . , TlGaSe2 볿 = 107 = 119 , , . , = 110 = 117 (d, d, 1/4), d 0.02. [14 - 17] , = 117 = 110 d, = 107 , , 111.3 . , , , [5].
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, TlGaSe2 65 340 200215 , 240-250 , , = 107119 , = 120246 , = 101340 , = 107253 . , 120 , 120-242 .
TlGaS2 TlGaSe2 3300 , 0.01 , 2%. , TlGaS2 , TlGaSe2 1 = 108.9 2 = 118.4 Cp (T) 10.5% 3% . TlGaSe2 .[6, 8-11]
[12] TlGaSe2 12 300 , , , . , e (T) tg d 1 1 , 볿 = 110 = 120 . , = 110 . (DSC-2), Cp (T) . a, b, c , 2/ , . , Tl , Tl, .[13]
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TlGaSe2 TlInS2 , , [14] , TlInS2 .
, , 볿 TlGaSe2 TlInS2 TlInS2 , , , = 110 TlGaSe2 , = 7 / . TlInS2, = 1 /. [6, 11,9]
TlInS2 TlGaSe2 . [20] TlInS2 䳿 = 0.6 = 300 , . [19]
TlMX2 (M = Ga, In, X = Se, S) 䳿 , , ᒺ TlInS2, TlGaSe2, TlGaS2 = 300 = 110 , TlInSe2 = 110 8 . , 2/ . (), , TlGaSe2 , p £ p £ 0.66 . TlInS2 ( 2.5 ) , , 0.6 1 2.5 . , TlInS2 TlGaSe2.[11]
TlInS2, TlGaSe2, TlGaS2 520 1.2 . ³, TlInS2, TlGaSe2 TlGaS2, GaS. , , , , 0.35, 0.4 0.65 TlGaS2, TlGaSe2 TlInS2.