CH3COONa. , . 3 2 0.1 FeCl3. - ( ).
.
, . . , - .
, , . (III) .
, ( ).
4. 20
5. 20
1. :
) CH3 C(Cl)=CH COOH
) CH2Br CH2 CH2 COOH
) CH3COO CH=CH2
) H5C2OOC CH2 COOC2H5
:
3--2-
4-
2. :
) 2- ,
) α- ,
) 3- ,
) 2--4- ,
) 2- ,
) 4,4- ,
) - ,
) ,
) ,
) ,
) 4- ,
) ,
) 2,3--3- ,
) β- ,
) ,
) .
, , IUPAC.
:
) 2-
) α-
) 3-
) 2--4-
) 2-
) 4,4-
) -
3)
) (- )
) (- )
) 4-
) (2- )
) 2,3--3-
) β- (3- )
) ( )
) ( )
3. :
) 3CL + C2H5Cl →
) (CH3CO)2O + C2H5NH2→
) CH3CONH2 + C3H7OH →
|
|
|
) CH3COCl + C6H5OH →
) CH3COOH + CH2=CH2→
:
)3COCl + C6H5OH H3COOC6H5 + HCl
)CH3CONH2 + C3H7OH CH3COOC3H7 + NH3
4. ?
A) CH3CH2COCl + NH3→
) CH3CH2COOCH3 + NH3→
) CH3CH2CH=O + NH3→
) (CH3CO)2O + NH2NH2→
) CH3CH2COOH + NH3 ( ) →
:
) H3CH2COCl + NH3H3CH2CO NH2 + HCl
) H3CH2COCH3 + NH3 H3CH2CO NH2 + CH4
5. ?
A) (CH3(CH2)2COOH + C2H5OH→
)CH3COOH + C3H7OH→
)CH3CH2COOH + C3H7OH→
)CH3COOH + C4H9OH→
)CH3CH=O + C4H9OH→
:
) H3CO + C3H7OH CH3COOC3H7 + 2
6. 65 (1) : 65Cl (2), (65)2 (3), 65ONH2 (4), C6H5COOC2H5 (5)
A) 2>3>1>4>5
) 1>2>5>3>4
) 2>3>1>5>4
) 3>2>5>4>1
)) 3>2>1>5>4
:
) 2>3>1>5>4
7. ?
)
)
)
)
) -
:
)
) -
8. :
)CH3CH2COOH CH3CHClCOOH
) CH3CH2CH2COOH CH3CH2CH(NO2)COOH
) (CH3)3CCOOH CH3CH2CH2CH2COOH
) CH3CH2COOH HOOCCH2COOH
:
) H3CHlCO
) CH3CH2CH2COOH
) CH3CH2CH2CH2COOH
)HOOCCH2COOH
9. :
CH3CH2CH2CH2CH2COOH + PCl5
CH3(CH2)7CH2COOH + SOCl2
C6H5COONH4+ +
CH3(CH2)4CH2CONH2 + LiAlH4 / Et2O
:
CH3CH2CH2CH2CH2COOH+ PCl5 CH3CH2CH2CH2CH2COCl + POCl3+ HCl
CH3(CH2)7 CH2COOH + SOCl2 CH3(CH2)7 CH2COCl + SO2 + HCl
C6H5COO-NH4+ + C6H5CONH2 + H2O
CH3(CH2)4 CH2CONH2 + LiAlH4/Et2O CH3(CH2)4 CH2COC2H5 + C2H5COOH
6. 5
7. 10
180 .
