1 3 | 2/3 | /3 | , 3/2 | ||
25´25´3 | |||||
80,5 | - | ||||
120 |
. 6 = f(t) . 7
: = f(t)
1 25´25´3 ; 2 42 ; ;
3 43 ;
4 41 . 10 3/2 . 90 3/2 . 1 25´25´3 ;
2 42 ;
3 41 ;
4 41 ;
5 29 ;
6 24 .
. 8 D .
.10 2= f(t)
50 3/2
. 9 2= f(t)
25´25´3 50 3/2
25´25´3
7.
/3 1
, | 2 , /3 |
69,5 | |
60,7 | |
53,7 | |
48,0 | |
43,4 | |
39,3 | |
35,9 | |
33,2 | |
30,8 | |
28,6 | |
26,6 |
. 11 , .
.
. 12 D H2S
0,1 /
8.
, 3/ | f, 2 | f0,324, 2 | , 3/ | f, 2 | f0,324, 2 |
0,167 | 0,56 | 5,01 | 1,68 | ||
0,334 | 0,70 | 5,83 | 1,77 | ||
0,501 | 0,80 | 6,68 | 1,85 | ||
0,668 | 0,88 | 7,50 | 1,92 | ||
0,835 | 0,94 | 8,35 | 1,99 | ||
1,25 | 1,07 | 10,0 | 2,11 | ||
1,67 | 1,18 | 11,7 | 2,22 | ||
2,50 | 1,35 | 13,4 | 2,32 | ||
3,34 | 1,48 | 15,0 | 2,40 | ||
4,17 | 1,59 | 16,7 | 2,49 |
9.
2
1
/3 | |
|
|
. 13 H2S
H2S, 1
. 14 H2S %
pH
1
1. 25*25*3 : q = 310 3/, 2,5 -/, 0,8 -/. 2
= 27 /. , = 3 / , t = 350 .
2. :
q = 133 3/, 22 /, - 5,4, 80 ,
= 0,1 /.
3. :
q = 210 3/, = 10,4/, = 0,3 /, t = 300 ( ).
- 25*25*3 .
2
1. :
q = 155 3/, 20 /, - 5,2, 100 , = 0,1 /.
2. : q = 170 3/,
= 400 /, = 5 /. 350 .
3. , : q = 350 3/, = 320 /, = 10 /. 300 .
3
1. : q = 120 3/,
= 180 /, = 3 /. 280 .
2. :
q = 570 3/, 7,2, 6,7 -/, 230 ./,
= 26 /, Fe=3,2 /, 25*25*3 , 160 .
3. : q= 120 3/, = 365 /, = 5 /, t = 340, f = 2 2.
4
1. 25*25*3 q = 220 3/, 3,5 -/, 0,65 -/. 2
= 38 /. , = 5 /. , t = 300 .
2. :
q = 118 3/, = 11,4/, = 0,3 /, t = 300 ( ). - 25*25*3 .
3. :
q = 530 3/, 7,2, 5,6 -/, 250 ./,
|
|
= 25 /, Fe=3,5 /, 25*25*3 , 120 .
5
1. :
q = 144 3/, 33 /, - 5,8, 120 , = 0,1 /.
2. :
q =567 3/, 7,2, 5,9 -/, 200 ./,
= 25,5 /, Fe=3,8/, 25*25*3 , 200 .
3. :
q = 330 3/, = 8,2 /, = 0,1 /, t = 300 ( ). - 25*25*3 .
6
1. : q = 132 3/,
= 250 /, = 410 /. 350 .
2. :
q = 121 3/, = 9,2 /, = 0,05 /, t= 300 ( ). - 25*25*3 .
3. , : q = 250 3/, = 260 /, = 3 /. 250 .
7
1. 25*25*3 q = 300 3/, 3 -/, 0,8 -/. 2
= 35 /. , = 5 /. , t = 45 0 .
2. : q = 250 3/,
= 300 /, = 3 /. 250 .
3. :
q = 580 3/, 7,2, 6,6 -/, 220 ./,
= 25 /, Fe=3,6 /, 25*25*3 , 150 .
8
1. : q = 220 3/,
= 320 /, = 5 /. 200 .
2. :
q = 180 3/, = 9,9 /, = 0,01/, t = 200 ( ). - 25*25*3 .
3.
q = 58 3\. 7,2, 6 \, 27 \, Fe 4,0 \, 200 \, 120. - 24 .
9
1. :
q = 128 3/, 25/, - 6,4, 180 , = 0,1 /.
2. : q = 110 3/, = 165 /, = 3 /, t = 300, f = 2 2.
3. :
q = 510 3/, 7,2, 6,9 -/, 120 /,
= 25 /, Fe=3,4 /, 25*25*3 , 150 .
10
1. 25*25*3 q = 300 3/, 2,7 -/, 0,62 -/. 2
|
|
= 33 /. , = 3 /. , t = 210 .
2. : q= 150 3/, = 165 /, = 3 /, t = 280, f = 2 2.
3. :
q =525 3/, 7,2, 6,7 -/, 300 /,
= 28 /, Fe=4,2 /, 25*25*3 , 160 .
11
1. :
q = 135 3/, 22 /, - 5,6, 80 ,
= 0,1 /.
2. , : q = 230 3/, = 320 /, = 10 /. 180 .
3. 25*25*3 q = 250 3/, 2,75 -/, 0,72 -/. 2
= 28 /. , = 3 /. , t = 160 .
12
1. :
q =600 3/, 7,2, 6 -/, 300 /,
=25 /, Fe=3,4 /, 25*25*3 , 150 .
2. : q = 130 3/, =363 /, = 5 /, t = 300, f = 2 2.
3. 25*25*3 : q = 330 3/, 3,0 -/, 0,78 -/. 2
= 28 /. , = 5 / , t = 150 .
13
1. 25*25*3 : q = 250 3/, 2,8 -/, 0,78 -/. 2
= 36 /. , = 5 / , t = 250 .
2. : q= 110 3/, = 265 /, = 5 /, t = 350, f = 2 2.
3. 1.
q =49 3\. 7,2, 6,3 \, 25 \, Fe 5,2 \, 250 \, 150. - 41 .
14
1. q =54 3\. 7,2, 4,7 \, 23 \, Fe 4,5 \, 300 \, 200. - 29 .
|
|
2. :
q = 150 3/, = 10,5/, = 0,1 /, t= 300 ( ). - 25*25*3 .
3. :
q = 262 3/, 25/, - 6,2, 160 ,
= 0,1 /.
15
1. :
q = 620 3/, 7,2, 6,3 -/, 200 /,
= 24/, Fe=3,5/, 25*25*3 , 170 .
2. : q= 140 3/, = 163 /, = 3 /, t = 350, f = 2 2.
3. :
q = 250 3/, = 220 /, = 5 /. 100 .
16
1. 25*25*3 : q = 330 3/, 3,2 -/, 0,68 -/. 2
= 36 /. , = 10 / , t = 120 .
2. : q = 142 3/, 35/, - 5,9,
60 , = 0,2 /.
3. , : q = 170 3/, = 188 /, = 5 /. 180 .
17
1. :
q =584 3/, 7,2, 4,6 -/, 150 /,
= 25 /, Fe=4,6 /, 25*25*3 , 150 .
2. , : q = 157 3/, = 180 /, = 3 /. 180 .
3. : q = 200 3/,
= 290 /, = 5 /. 250 .
18
1. :
q = 265 3/, 24 /, - 6,2, 80 , = 0,1 /.
2. : q = 150 3/,
= 100 /, = 3 /. 250 .
3. : q= 130 3/, =226 /, = 3 /, t = 330, f = 2 2.
19
1. 25*25*3 : q = 220 3/, 2,0 -/, 0,75 -/. 2
= 32 /. , = 5 /. , t = 300 .
2. :
q = 250 3/, 24 /, - 5,7, 80 ,
= 0,1 /.
3. : q= 150 3/, =295 /, = 5 /, t = 350, f = 2 2.
20
1. :
q = 530 3/, 7,2, 4,4 -/, 300 /,
=25 /, Fe=4,2 /, 25*25*3 , 190 .
2. :
|
|
q = 160 3/, = 12 /, 0,1 /, t = 300 ( ). - 25*25*3 .
3. , : q = 250 3/, = 230 /, = 5 /. 200 .
21
1. 25*25*3 : q = 323 3/, 3,0 -/, 0,78 -/. 2
= 38 /. , = 5 /. , t = 220 .
2. :
q = 135 3/, 18 /, - 5,4, 60 ,
= 0,1 /.
3. , , : q = 170 3/, = 350 /, = 10 /. 240 .
22
1. :
q =540 3/, 7,2, 4,6 -/, 200 /,
= 25 /, Fe= 4,3 /, 25*25*3 , 180 .
2. , : q = 150 3/, = 180 /, = 3 /. 280 .
3. : q = 200 3/,
= 290 /, = 5 /. 250 .
23
1. :
q = 145 3/, 25 /, - 6,0, 80 , = 0,1/.
2. : q = 150 3/,
= 220 /, = 5 /. 250 .
3. : q = 153 3/, = 226 /, = 5 /, t = 190, f = 2 2.
24
1. 25*25*3 : q = 220 3/, 2,9 -/, 0,75 -/. 2
= 36 /. , = 5 /. , t = 200 .
2. :
q = 160 3/, = 8,5/, = 0,05 /, t= 300 ( ). - 25*25*3 .
3. q =54 3\. 7,2, 5,3 \, 25 \, Fe 4,2 \, 220 \, 170. - 41 .
25
1. :
q = 570 3/, 7,2, 4,6 -/, 250 /,
= 23 /, Fe=4,5 /, 25*25*3 , 160 .
2. :
q = 160 3/, = 6,8 /, = 0,05 /, t= 280 ( ). - 25*25*3 .
3. , : q = 132 3/, = 230 /, = 10 /. 160 .
26
1. 25*25*3 : q = 310 3/, 3,8 -/, 0,68 -/. 2
= 36 /. , = 10 / , t = 200 .
2. :
q = 162 3/, 35/, - 5,9, 60 ,
= 0,1 /.
3. , : q = 162 3/, = 198 /, = 5 /. 180 .
27
1. :
q =523 3/, 7,2, 6,6 -/, 150 ./,
= 25 /, Fe= 3,8 /, 25*25*3, 150 .
2. , : q = 150 3/, = 200 /, = 10 /. 200 .
3. : q = 200 3/,
= 190 /, = 10 /. 250 .
28
1. :
q = 155 3/, 25 /, - 6,2, 80 ,
= 0,1 /.
2. : q = 150 3/,
= 250 /, = 5 /. 250 .
3. : q= 138 3/, = 226 /, = 5 /, t = 280, f = 2 2.
29
1. 25*25*3 : q = 245 3/, 3,2 -/, 0,90 -/. 2
= 38 /. , = 5 / , t = 350 .
2. :
q = 238 3/, 24 /, - 5,8, 180 ,
= 0,1 /.
3. : q = 187 3/, = 295 /, = 5 /, t = 220, f = 2 2.
30
1. :
q = 630 3/, 7,2, 6,4 -/, 240 ./,
=25 /, Fe=3,8 /, 25*25*3 , 190 .
2. :
q = 146 3/, = 7,5 /, = 0,3 /, t = 200 ( ). - 25*25*3 .
3. , : q = 160 3/, = 230 /, = 10 /. 150 .
31
1. 25*25*3 : q = 320 3/, 3,2 -/, 0,68 -/. 2
= 36 /. , = 5 / , t = 120 .
2. :
q = 146 3/, 20 /, - 5,9, 60 , = 0,1 /.
3. , : q = 159 3/, = 288 /, = 10 /. 280 .
32
1. :
q =670 3/, 7,2, 6,3 -/, 250 ./,
= 25 /, Fe = 4,2 /, 25*25*3 , 150 .
2. , : q = 150 3/, = 180 /, = 3 /. 120 .
3. : q = 200 3/,
= 194 /, = 10 /. 250 .
33
1. :
q = 165 3/, 17 /, = 6,2, t = 80 , = 0,1/.
2. : q = 135 3/,
= 350 /, = 3 /. 250 .
3. : q= 138 3/, = 136 /, = 3 /, t = 350, f = 2 2.
34
1. 25*25*3 : q = 230 3/, 3,2 -/, 0,68 -/. 2
= 35 /. , = 10 / , t = 220 .
2. :
q = 140 3/, 25/, - 5,9, 60 ,
= 0,1 /.
3. , : q = 172 3/, = 320 /, = 10 /. 280 .
35
1. 25*25*3 : q = 240 3/, 3,9 -/, 0,85 -/. 2
= 34 /. , = 3 / , t = 350 .
2. :
q = 250 3/, 24 /, - 6,5, 80 ,
= 0,1 /.
3. : q= 150 3/, =295 /, = 10 /, t = 300, f = 2 2.
36
1.
q =54 3\. 7,2, 6,0 \, 25 \, Fe 4,2 \, 320 \, 170. - 43 .
2. :
q = 142 3/, = 9,8 /, = 0,1 /, t = 250 ( ). - 25*25*3 .
3. , : q = 154 3/, = 330 /, = 10 /. 280 .
37
1. 25*25*3 : q = 450 3/, 3,2 -/, 0,65 -/. 2
= 38 /. , = 5 / , t = 420 .
2. :
q = 145 3/, 22 /, - 5,9, 60 , = 0,1 /.
3. , : q = 350 3/, = 260 /, = 5 /. 180 .
38
1. :
q =585 3/, 7,2, 5,6 -/, 380 ./,
= 25 /, Fe=4,1 /, 25*25*3 , 150 .
2. , : q = 150 3/, = 280 /, = 3 /. 220 .
3. : q = 260 3/,
= 290 /, = 5 /. 300 .
39
1. :
q = 165 3/, 18 /, - 6,2, 80 , = 0,1 /.
2. : q = 158 3/,
= 360 /, = 10 /. 250 .
3. : q= 230 3/, = 224 /, = 5 /, t = 250, f = 2 2.
40
1. 25*25*3 : q = 420 3/, 2,9 -/, 0,65 -/. 2
= 40 /. , = 5 /. , t = 350 .
2. :
q = 253 3/, 24 /, - 6,5, 80 , = 0,1 /.
3. : q= 152 3/, =395 /, = 10 /, t = 120, f = 2 2.
41
1. :
q- 555 3/, 7,2, 6,4 -/, 240 ./,
= 25 /, Fe=3,4 /, 25*25*3 , 160 .
2. :
q = 166 3/, = 8,5/, = 0,05 /, t= 300 ( ). - 25*25*3 .
3. , : q = 250 3/, = 230 /, = 5 /. 200 .
42
1. 25*25*3 : q = 320 3/, 3,2 -/, 0,68 -/. 2
= 35 /. , = 5 / , t = 380 .
2. :
q = 142 3/, 25/, - 5,9, 60 , = 0,1 /.
3. , : q = 173 3/, = 488 /, = 10 /. 280 .
1. | .. : ./ ..,....:- , 1996. 680. |
2. | .. , : .. .2, . . / .., .., .. . .: - , 2004. 496. |
3. | 2.04.0284* . . .: , 2000. 127. |
4. | .., .., .. .: . 2- ., . .: , 2006. 309.: . |
5. | .. . . : , 2003. |
6. | ( 2.04.0284) |