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0701

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..., ˺ .. ..( ).

 

 

2016 . 1

 

 

..., ____________ ..˺

()

 

 

- ______________ ..

()


1. ()      
   
1    
2    
2.    
   
1    
3.    
   
1    
2    

1

: ()

50-60% , - 85-90%.

, .

- . , .

 

1. .

2. .

3. .

4. .

5. .

6. [5].

, , , - , . - , . , , , , "" , , .

, , :

- 70%;

- 20%;

- 10%.

, , , .

.

, , .

:

1) - , , , 250 . ;

2) . . , 500 3, .

3) ( ) - , .

 

, 250 , , , , , .

, :

1. (, , );

2. ;

3. -;

4. ;

5. - .

, [5].

 
Q
T=500ºC

- , - , - ,

Q - , ,

- ;

;

;

- , - .

1 - .

 

, , Y, ./, [5]:

 

Y=γ*σ*f*M, (1)

 

γ , 48, ./.;

σ [5], σ=4;

f , . 1 /, :

 

f =[100/(100+φ*h)]*[4/(1+υ)], (2)

 

h , ( );

υ , 3 /;

φ , :

 

φ=1+∆T/75, (3)

 

∆T , C, :


∆T=T-t (4)

 

T - 13 00 [3], 0;

t , C.

M , , ./, [5]:

N

M=∑i*mi (5)

i=1

 

i i- , ./;

N ;

mi i- , /.

, , ./, :

 

=Y1Y2, (6)

 

Y1, Y2 , (1, 2)

, ./, :

 

. = /Q, (7)

 

Q , /.

, /, 1 :

 

1=Q(1*+Nox1*NOx+SO21*SO2+CHx1*CHx+1*) (8)

 

, ./, 1 :

 

Y1=γ*σ*f*M1 (9)

 

, /, 2 :

 

2=Q(2*+Nox2*NOx+SO22*SO2+CHx1*CHx+2*)(10)

 

, ./, 2 :

 

Y2=γ*σ*f*M2 (11)

 

, ./, :

 

=Y1Y2 (12)

 

, ./, :

 

. = /Q, (13)

4.

( %=4,5%)

Q=50000 /

t=35C

T=500C

σ=4

γ=48 ./.

h=20

υ=3 /

 

()%

CH3SH = 12+3+32 +1 ==48

1.1. () :

m 4,5 = Q * %= 50000 / * 4,5% / 100% = 2250/

1.2. SO2 :

CH3SH + 3O2 → SO2 +CO2 + 2H2O

:

m 4,5 * 103 * 22,4 / = 2250/ * 103 * 22,4 / 48 = 1050000 3/

1.3. SO2:

mSO2 4,5= 1050000 3/ * 64 10-3/ 22,4 = 3000 /

1.4. SO2:

SO24,5 = m SO2 / Q = 3000 / * 103 / 50000 / = 60 /

1.5. O:

O= Q * * = 50000 / *23*1*10-3 = 1150,00 ../

NOx:

NOx= Q * NOx * NOx = 50000 / *41*41*10-3 = 84050,00 ../

SO2:

SO2 4,5=Q * SO2 * SO2 = 50000 / * 60 *22,8*10-3 = 68400 ../

CHx:

CHx= Q * CHx * CHx = 50000 / *11*3,16*10-3 = 1738,00 ../

:

= Q * * = 50000 / *8*250*10-3 = 100000,00 ../

4,5:

ΣM4,5=SO2+O+NOx+CHx+= 68400 +1150+84050+1738+100000 =

= 255338../

1.6. [5]:

φ=1+∆T/75=1+465C/75=7,2

∆T=T-t=500C-35C=465C,

, , (3) [5]:

f=[100/(100+7,2 20)]*[4/(1+3)]= 0,41

1.7. :

Y=γ*σ*f*ΣM

4,5%= 484 0,41 255338=20092170,49 ./

1.8. 4,5% () :

=Q*(*+Nx*Nox+SO2*SO2+CHx*CHx+*),

α=95%

mSO2 = (1-95/100) *mSO2=(1-95/100) *3000 /= 150 /,

: SO2 = 150000//50000/=3/

SO2=50000/(3*22,8)10-3=34200,00 ../;

SO2=484*0,41*34200,00 =269114,75 ./

Σ=50000/((10*1+15*41+ 3 *22,8+3*3,16+1*250)10-3=

= 47644,00 ../;

:

4,5%=484* 0,41 *47644,00 =3749036,07 ./

:

=4,5%= 20092170,49 - 3749036,07=16343134,43 ./

:

=16343134,43/50000=326,86 ./

( %=3,5%)

1.1. () :

m 3,5 = Q * %= 50000 / * 3,5% / 100% = 1750,00 /

1.2. SO2 :

CH3SH + 3O2 → SO2 +CO2 + 2H2O

:

m 3,5 * 103 * 22,4 / = 1750,00/ * 103 * 22,4 / 48 = 816666,67 3/

1.3. SO2:

mSO2 3,5= 816666,67 3/ * 64 10-3/ 22,4 = 2333,33 /

1.4. SO2:

SO2 3,5 = mSO2 / Q = 2333,33 / * 103/ 50000 / = 46,67 /


1.5. O:

O= Q * * = 50000 / *23*1*10-3 = 1150,00 ../

NOx:

NOx= Q * NOx * NOx = 50000 / *41*41*10-3 = 84050,00 ../

SO2:

SO2 3,5=Q * SO2 * SO2 = 50000 / * 46,67 *22,8*10-3 = 53200,00 ../

CHx:

CHx= Q * CHx * CHx = 50000 / *11*3,16*10-3 = 1738,00 ../

:

= Q * * = 50000 / *8*250*10-3 = 100000,00 . ./

3,5:

ΣM3,5=SO2+O+NOx+CHx+= 53200,00 +1150+84050+1738+100000 =

= 240138,00../

1.6. [5]:

φ=1+∆T/75=1+465C/75=7,2

∆T=T-t=500C-35C=465C,

, , (3) [5]:

f=[100/(100+7,2 20)]*[4/(1+3)]= 0,41

1.7. :

Y=γ*σ*f*ΣM

3,5%= 484 0,41 240138,00=18896104,92 ./

1.8. :

=4,5%3,5%= 20092170,49 - 18896104,92 = 1196065,57 ./

1.9. :

.= /Q=1196065,57/50000=23,92 ./


( %=1,0%)

1.1. () :

m 1,0 = Q * %= 50000 / * 1,0% / 100% = 500,00 /

1.2. SO2 :

CH3SH + 3O2 → SO2 +CO2 + 2H2O

:

m 1,0 * 103 * 22,4 / = 500,00 / * 103 * 22,4 / 48 = 233333,333/

1.3. SO2:

mSO2 1,0= 233333,33 3/ * 64 10-3/ 22,4 = 666,67 /

1.4. SO2:

SO2 1,0 = mSO2 / Q = 666,67 / * 103/ 50000 / = 13,33 /

1.5. O:

O= Q * * = 50000 / *23*1*10-3 = 1150,00 ../

NOx:

NOx= Q * NOx * NOx = 50000 /*41*41*10-3 = 84050,00 ../

SO2:

SO2 1,0=Q * SO2 * SO2 = 50000 / * 13,33 *22,8*10-3 = 15200,00 ../

CHx:

CHx= Q * CHx * CHx = 50000 / *11*3,16*10-3 = 1738,00 ../

:

= Q * * = 50000 / *8*250*10-3 = 100000,00 ../

1,0:

ΣM1,0=SO2+O+NOx+CHx+= 15200,00 +1150+84050+1738+100000=

= 202138,00../

1.6. [5]:

φ=1+∆T/75=1+465C/75=7,2

∆T=T-t=500C-35C=465C,

, , (3) [5]:

f=[100/(100+7,2 20) ]*[4/(1+3)]= 0,41

1.7. :

Y=γ*σ*f*ΣM

1,0%= 484 0,41 202138,00= 15905940,98 ./

1.8. :

=4,5%1,0%= 20092170,49 - 15905940,98 = 4186229,51 ./

1.9. :

.= /Q=4186229,51/50000=83,72 ./

 

( %=0,1%)

1.1. () :

m 0,1 = Q * %= 50000 / * 0,1% / 100% = 50,00/

1.2. SO2 :

CH3SH + 3O2 → SO2 +CO2 + 2H2O

:

m 0,1 * 103 * 22,4 / = 50,00 / * 103 * 22,4 / 48 = 23333,33 3/

1.3. SO2:

mSO2 0,1= 23333,33 3/ * 64 10-3/ 22,4 = 66,67 /

1.4. SO2:

SO2 0,1 = mSO2 / Q = 66,67 / * 103/ 50000 / = 1,33 /

1.5. O:

O= Q * * = 50000 / *23*1*10-3 = 1150,00 . ./

NOx:

NOx= Q * NOx * NOx = 50000 / *41*41*10-3 = 84050,00 ../

SO2:

SO2 0,1=Q * SO2 * SO2 = 50000 / * 1,33 *22,8*10-3 = 1520,00 ../;

CHx:

CHx= Q * CHx * CHx = 50000 / *11*3,16*10-3 = 1738,00 . ./

:

= Q * * = 50000 / *8*250*10-3 = 100000,00 ../

0,1:

ΣM0,1=SO2+O+NOx+CHx+= 1520,00 +1150+84050+1738+100000 =

= 188458,00. ./

1.6. [5]:

φ=1+∆T/75=1+465C/75=7,2

∆T=T-t=500C-35C=465C.

, , (3) [5]:

f=[100/(100+7,2 20)]*[4/(1+3)]= 0,41

1.7. :

Y=γ*σ*f*ΣM

0,1%= 4840,41188458,00=14829481,97 ./

1.8. :

=4,5%0,1%= 20092170,49 - 14829481,97 = 5262688,52 ./

1.9. :

.= /Q=5262688,52/50000=105,25 ./


 

 

MK, % . 0,1   3,5 4,5
, ./ 14829481,97 15905940,98 18896104,92 20092170,49
4,5 k       3749036,07

2 (. / ) ( ) , % .





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