NH3, .
,
- NH2 ( ); - NHR ( ); - NR'R" ( ).
, , , .
- NH2, , . >NH .
N2.
3
ç .
2--3-.
ç :
N2 1--2,3--3-.
, , .
3NH2 ; 37NH2 ; 3NH25
(3 )2NH ; (3 )3N .
.
65NH2 .
, , . . .
, , ; .
. CH3NH2 , ; , , , , .
(CH3)3N , , , .
1. () - .
:
3I + NH3 = [CH3NH3]I
:
[CH3NH3]I + NH3 D CH3NH2 + NH4I
CH3NH2 + 3I D [(CH3)2NH2]I
[(CH3)2NH2]I + NH3 D (CH3)2NH + NH4I
(CH3)2NH + 3I D [(CH3)3NH]I
[(CH3)3NH]I + NH3 D (CH3)3N + NH4I
(CH3)3N + 3I D [(CH3)4N]I
:
[CH3NH3]I + NaOH = CH3NH2 + NaI + H2O
( ).
, , .
(CH3)3N + 16 33Cl D [(CH3)3N - 16 33]Cl
|
|
, , . , .
, , ,
= 5,5.
, . , .
2. ( )
3NO2 + 3H2 = CH3NH2 + 22