1772 . .
0,03%.
78% 75,5% .
, .
, .
.
:
1. 1772 . .
2. 78% 75,5% .
3. , .
.
III. . , , , , , , , . .
7 N 1S2 2S2 2P3
↑↓ | ↑ | ↑ | ↑ |
|
P
, . . (n = 2) d - . , V.
:
-3 0 +1 +2 +3 +4 +5
NH3 N2 N2O NO N2O3 NO2 N2O5
-3 0 +1 +2 +3 +4 +5
: - 3 +3 +5; : +2 +4 .
: N2 , , , . −1960C :
: . , , .. :
π N N N ≡ σ N N20 π |
.
N2, .
N20 :
t0, P, -3 +1
a) N20 + 3H20 2NH3
t0=780-8000C
/ : N20 + 3 ═ 3N2
N20 :
t0 ()
) : N20 + 20 ═ 2NO (II)
.
+3 -1
) : N20 + 3 F20 ═ 2 NF3 (III)
:
1.
:
-3 0 +1 +2 +3 +4 +5
NH3 N2 N2O NO N2O3 NO2 N2O5
-3 0 +1 +2 +3 +4 +5
|
|
2. : - 3 +3 +5; : +2 +4 .
3. .
4. N2,