: 0.7 16-, 17- 0.11 (1.5 ) 5 (). , .
6--6 --5--2,3- (28).
56%... 170-171 . -, ν, -1: 2205 (C≡N); 2913, 3026, 3276 (C-H). 1 (DMSO- d6, δ, .., J, ): 3.83 (, 3, O); 3.88 (, 3, O); 4.45 (, 2, 2); 7.26-7.38 (, 5H, HAr); 7.84 (, 1, ). 13 (DMSO- d6, δ, ..) 138.1, 140.2 (2); 48.5, 86.9, 116.5, 117.5, 117.9, 124.5, 126.9, 127.6, 128.3, 129.6, 129.8, 150.6, 180.7. -, m/z (I, %): 342 (M+, 7). , %: C 60.04; H 4.45; N 8.08; S 9.60. C17H14N2O4S. , %: C 59.64; H 4.12; N 8.18; S 9.37.
3--2--2 --5,6- (28). 49%. 1 (DMSO- d6, δ, .., J, ): 1.36-1.50 (, 5, 2); 1.67-1.81 (, 5, 2); 3.29 (. , 1, ); 3.83 (, 3, O); 3.88 (, 3, O); 7.73 (, 1, ). 13 (DMSO- d6, δ, ..) 24.2, 25.5, 31.5, 53.7, 54.6, 62.1, 112.5, 115.5, 122.5, 141.3, 142.7, 144.7, 162.8, 163.1. -, m/z (I, %): 334 (M+, 8). (%): C, 57.51; H, 5.13; N, 8.17; S, 9.72. C16H19N3O. (%): C, 57.47; H, 5.43; N, 8.38; S, 9.59.
4.
: 307 /.
4.1
| 1. | |
| 2. | 166-167 |
| 3. | 0,5% |
| 4. | , , |
:
1. .
2. 6 .
3. , , , , , . 20-25 .
,
4.2
,
| 1. N --2- | 98% | , 98% | ||
| 2. | Acros organics | 99% | , =143, - 99% | |
| 3. | 21039-75 | 97% | , t 139,5, - 97% | |
| 4. - | Acros organics | 95% | , , =57,2 , - 95% | |
| 5. | 11547-65 | 96% | , =78,4; - . 96% |
|
|
|
